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  1. 紀要掲載論文
  2. 北見工業大学研究報告
  3. Vol.24

Discrimination of Multi-Reaction Pathways in the Oxidation of Carbon Monoxide on Zinc Oxide

https://kitami-it.repo.nii.ac.jp/records/6686
3d03b1f9-0197-4f7c-a849-def5cecd55ec
名前 / ファイル ライセンス アクション
24-1-3.pdf 24-1-3.pdf (3.1 MB)
Item type 紀要論文 / Departmental Bulletin Paper(1)
公開日 2007-04-09
タイトル
タイトル Discrimination of Multi-Reaction Pathways in the Oxidation of Carbon Monoxide on Zinc Oxide
言語
言語 eng
資源タイプ
資源 http://purl.org/coar/resource_type/c_6501
タイプ departmental bulletin paper
著者 Masaki, HAKOZAKI

× Masaki, HAKOZAKI

WEKO 33713

Masaki, HAKOZAKI

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Boris, GOLMAN

× Boris, GOLMAN

WEKO 33714

Boris, GOLMAN

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Tohru, KANNO

× Tohru, KANNO

WEKO 33715

Tohru, KANNO

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Masayoshi, KOBAYASHI

× Masayoshi, KOBAYASHI

WEKO 33716

Masayoshi, KOBAYASHI

Search repository
Masaki, HAKOZAKI

× Masaki, HAKOZAKI

WEKO 33717

Masaki, HAKOZAKI

Search repository
Boris, GOLMAN

× Boris, GOLMAN

WEKO 33718

Boris, GOLMAN

Search repository
Tohru, KANNO

× Tohru, KANNO

WEKO 33719

Tohru, KANNO

Search repository
Masayoshi, KOBAYASHI

× Masayoshi, KOBAYASHI

WEKO 33720

Masayoshi, KOBAYASHI

Search repository
抄録
内容記述タイプ Abstract
内容記述 Anomalous behavior of heterogeneously catalyzed CO oxidation on ZnO at the steady state and the transient state has been interpreted by the multi-reaction pathway model based on the different intermediates (Is).The reaction mechanism consists of a Langmuir-Hinshelwood(L-H)part,in which Is O(neutrally adsorbed oxygen),and an Eley-Rideal(E-R) part with O^-. The mode of transient response curve is sensitively shifted among a monotonous,an overshoot, a false start and a complex type according to the concentrations of CO and O_2. The proposed model consistently explains the anomalous steady state rate kinetics and the mode of transient response curves,and all the kinetic parameters of the reaction sequences are evaluated by using a computer simulation technique,indicating the good fit to the experimental curves.
書誌情報 北見工業大学研究報告

巻 24, 号 1, p. 17-24, 発行日 1992-09
フォーマット
内容記述タイプ Other
内容記述 application/pdf
出版者
出版者 北見工業大学
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