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Discrimination of Multi-Reaction Pathways in the Oxidation of Carbon Monoxide on Zinc Oxide
https://kitami-it.repo.nii.ac.jp/records/6686
3d03b1f9-0197-4f7c-a849-def5cecd55ec
名前 / ファイル | ライセンス | アクション | |
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Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||
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公開日 | 2007-04-09 | |||||
タイトル | ||||||
タイトル | Discrimination of Multi-Reaction Pathways in the Oxidation of Carbon Monoxide on Zinc Oxide | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源 | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | departmental bulletin paper | |||||
著者 |
Masaki, HAKOZAKI
× Masaki, HAKOZAKI× Boris, GOLMAN× Tohru, KANNO× Masayoshi, KOBAYASHI× Masaki, HAKOZAKI× Boris, GOLMAN× Tohru, KANNO× Masayoshi, KOBAYASHI |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | Anomalous behavior of heterogeneously catalyzed CO oxidation on ZnO at the steady state and the transient state has been interpreted by the multi-reaction pathway model based on the different intermediates (Is).The reaction mechanism consists of a Langmuir-Hinshelwood(L-H)part,in which Is O(neutrally adsorbed oxygen),and an Eley-Rideal(E-R) part with O^-. The mode of transient response curve is sensitively shifted among a monotonous,an overshoot, a false start and a complex type according to the concentrations of CO and O_2. The proposed model consistently explains the anomalous steady state rate kinetics and the mode of transient response curves,and all the kinetic parameters of the reaction sequences are evaluated by using a computer simulation technique,indicating the good fit to the experimental curves. | |||||
書誌情報 |
北見工業大学研究報告 巻 24, 号 1, p. 17-24, 発行日 1992-09 |
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フォーマット | ||||||
内容記述タイプ | Other | |||||
内容記述 | application/pdf | |||||
出版者 | ||||||
出版者 | 北見工業大学 |