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Discrimination of Multi-Reaction Pathways in the Oxidation of Carbon Monoxide on Zinc Oxide
https://kitami-it.repo.nii.ac.jp/records/6686
https://kitami-it.repo.nii.ac.jp/records/66863d03b1f9-0197-4f7c-a849-def5cecd55ec
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
24-1-3.pdf (3.1 MB)
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| Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||
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| 公開日 | 2007-04-09 | |||||
| タイトル | ||||||
| タイトル | Discrimination of Multi-Reaction Pathways in the Oxidation of Carbon Monoxide on Zinc Oxide | |||||
| 言語 | en | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| 資源タイプ | ||||||
| 資源 | http://purl.org/coar/resource_type/c_6501 | |||||
| タイプ | departmental bulletin paper | |||||
| 著者 |
Masaki, HAKOZAKI
× Masaki, HAKOZAKI× Ｂｏｒｉｓ, ＧＯＬＭＡＮ× Tohru, KANNO× Masayoshi, KOBAYASHI× Masaki, HAKOZAKI× Boris, Golman× Tohru, KANNO× Masayoshi, KOBAYASHI |
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| 抄録 | ||||||
| 内容記述タイプ | Abstract | |||||
| 内容記述 | Anomalous behavior of heterogeneously catalyzed CO oxidation on ZnO at the steady state and the transient state has been interpreted by the multi-reaction pathway model based on the different intermediates (Is).The reaction mechanism consists of a Langmuir-Hinshelwood(L-H)part，in which Is O(neutrally adsorbed oxygen)，and an Eley-Rideal(E-R) part with O^-. The mode of transient response curve is sensitively shifted among a monotonous，an overshoot， a false start and a complex type according to the concentrations of CO and O_2. The proposed model consistently explains the anomalous steady state rate kinetics and the mode of transient response curves，and all the kinetic parameters of the reaction sequences are evaluated by using a computer simulation technique，indicating the good fit to the experimental curves. | |||||
| 言語 | en | |||||
| 書誌情報 |
ja : 北見工業大学研究報告 巻 24, 号 1, p. 17-24, 発行日 1992-09 |
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| フォーマット | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | application/pdf | |||||
| 著者版フラグ | ||||||
| 言語 | en | |||||
| 値 | publisher | |||||
| 出版者 | ||||||
| 出版者 | 北見工業大学 | |||||
| 言語 | ja | |||||
