@article{oai:kitami-it.repo.nii.ac.jp:00006686, author = {Masaki, HAKOZAKI and Boris, GOLMAN and Tohru, KANNO and Masayoshi, KOBAYASHI and Masaki, HAKOZAKI and Boris, GOLMAN and Tohru, KANNO and Masayoshi, KOBAYASHI}, issue = {1}, journal = {北見工業大学研究報告}, month = {Sep}, note = {application/pdf, Anomalous behavior of heterogeneously catalyzed CO oxidation on ZnO at the steady state and the transient state has been interpreted by the multi-reaction pathway model based on the different intermediates (Is).The reaction mechanism consists of a Langmuir-Hinshelwood(L-H)part,in which Is O(neutrally adsorbed oxygen),and an Eley-Rideal(E-R) part with O^-. The mode of transient response curve is sensitively shifted among a monotonous,an overshoot, a false start and a complex type according to the concentrations of CO and O_2. The proposed model consistently explains the anomalous steady state rate kinetics and the mode of transient response curves,and all the kinetic parameters of the reaction sequences are evaluated by using a computer simulation technique,indicating the good fit to the experimental curves.}, pages = {17--24}, title = {Discrimination of Multi-Reaction Pathways in the Oxidation of Carbon Monoxide on Zinc Oxide}, volume = {24}, year = {1992} }