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  1. 紀要掲載論文
  2. 北見工業大学研究報告
  3. Vol.17

Temperature Programmed Reaction Analysis of the Surface Intermediates Formed on Silver in the Oxidation of Acetaldehyde*

https://kitami-it.repo.nii.ac.jp/records/6578
https://kitami-it.repo.nii.ac.jp/records/6578
67fa6b94-745a-4148-878e-c92a56ce37ce
名前 / ファイル ライセンス アクション
17-1-5.pdf 17-1-5.pdf (5.5 MB)
Item type 紀要論文 / Departmental Bulletin Paper(1)
公開日 2007-04-09
タイトル
タイトル Temperature Programmed Reaction Analysis of the Surface Intermediates Formed on Silver in the Oxidation of Acetaldehyde*
言語
言語 eng
資源タイプ
資源 http://purl.org/coar/resource_type/c_6501
タイプ departmental bulletin paper
著者 Masahito, UJIIE

× Masahito, UJIIE

WEKO 33148

Masahito, UJIIE

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Tohru, KANNO

× Tohru, KANNO

WEKO 33149

Tohru, KANNO

Search repository
Masayoshi, KOBAYASHI

× Masayoshi, KOBAYASHI

WEKO 33150

Masayoshi, KOBAYASHI

Search repository
抄録
内容記述タイプ Abstract
内容記述 Two different transient response techniques, the transient response method and TPR, are applied to analyse the detailed structure of the intermediates which are stably formed on a silver surface in the oxidation of acetaldehyde. Analysis of the product distribution in the transient response method clearly shows that the intermediates consist of at least three different species : silver acetate form, acetaldehyde form and alcohol form. The TPR technique newly proposes two additional different species (designated In-α and In-β), in addition to the three species from the transient response method. Both species react with O_2 to produce CO_2 and H_2O, whereas they do not react with H_2. In the TPR spectra in the O_2 stream, In-α and In-β give peaks at 115℃ and 150℃, respectively,indicating different reactivity.
書誌情報 北見工業大学研究報告

巻 17, 号 1, p. 61-73, 発行日 1985-11
フォーマット
内容記述タイプ Other
内容記述 application/pdf
著者版フラグ
値 publisher
出版者
出版者 北見工業大学
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