{"created":"2021-03-01T05:59:00.880214+00:00","id":6578,"links":{},"metadata":{"_buckets":{"deposit":"be02e5da-1902-4bf3-b905-4490409da7a0"},"_deposit":{"id":"6578","owners":[],"pid":{"revision_id":0,"type":"depid","value":"6578"},"status":"published"},"_oai":{"id":"oai:kitami-it.repo.nii.ac.jp:00006578","sets":["7:15:38"]},"item_2_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1985-11","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"1","bibliographicPageEnd":"73","bibliographicPageStart":"61","bibliographicVolumeNumber":"17","bibliographic_titles":[{"bibliographic_title":"北見工業大学研究報告"}]}]},"item_2_description_14":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_2_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Two different transient response techniques, the transient response method and TPR, are applied to analyse the detailed structure of the intermediates which are stably formed on a silver surface in the oxidation of acetaldehyde. Analysis of the product distribution in the transient response method clearly shows that the intermediates consist of at least three different species : silver acetate form, acetaldehyde form and alcohol form. The TPR technique newly proposes two additional different species (designated In-α and In-β), in addition to the three species from the transient response method. Both species react with O_2 to produce CO_2 and H_2O, whereas they do not react with H_2. In the TPR spectra in the O_2 stream, In-α and In-β give peaks at 115℃ and 150℃, respectively，indicating different reactivity.","subitem_description_type":"Abstract"}]},"item_2_publisher_32":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"北見工業大学"}]},"item_2_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"publisher"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Masahito, UJIIE"}],"nameIdentifiers":[{"nameIdentifier":"33148","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Tohru, KANNO"}],"nameIdentifiers":[{"nameIdentifier":"33149","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Masayoshi, KOBAYASHI"}],"nameIdentifiers":[{"nameIdentifier":"33150","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2016-11-22"}],"displaytype":"detail","filename":"17-1-5.pdf","filesize":[{"value":"5.5 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"17-1-5.pdf","url":"https://kitami-it.repo.nii.ac.jp/record/6578/files/17-1-5.pdf"},"version_id":"513a99a2-11b0-4934-bd84-5ebb1ccc0811"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Temperature Programmed Reaction Analysis of the Surface Intermediates Formed on Silver in the Oxidation of Acetaldehyde*","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Temperature Programmed Reaction Analysis of the Surface Intermediates Formed on Silver in the Oxidation of Acetaldehyde*"}]},"item_type_id":"2","owner":"1","path":["38"],"pubdate":{"attribute_name":"公開日","attribute_value":"2007-04-09"},"publish_date":"2007-04-09","publish_status":"0","recid":"6578","relation_version_is_last":true,"title":["Temperature Programmed Reaction Analysis of the Surface Intermediates Formed on Silver in the Oxidation of Acetaldehyde*"],"weko_creator_id":"1","weko_shared_id":3},"updated":"2022-12-13T02:19:55.053774+00:00"}