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  1. 学術雑誌掲載済論文
  2. 洋雑誌

Transfer of alk-1-enyl group from boron to tin: A highly stereoselective synthesis of (E)-alk-1-enyltributylstannanes

https://kitami-it.repo.nii.ac.jp/records/8445
https://kitami-it.repo.nii.ac.jp/records/8445
dd85a860-c24f-4f8d-9e02-be2bb5b32939
名前 / ファイル ライセンス アクション
u07509st.pdf u07509st.pdf (82.0 kB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2016-08-31
タイトル
言語 en
タイトル Transfer of alk-1-enyl group from boron to tin: A highly stereoselective synthesis of (E)-alk-1-enyltributylstannanes
言語
言語 eng
キーワード
主題Scheme Other
主題 transfer
キーワード
主題Scheme Other
主題 (E)-alk-1-enyltributylstannane
キーワード
主題Scheme Other
主題 (E)-alk-1-enyldicyclohexylborane
キーワード
主題Scheme Other
主題 tributyltin methoxide
キーワード
主題Scheme Other
主題 halodestannylation
資源タイプ
資源 http://purl.org/coar/resource_type/c_6501
タイプ journal article
アクセス権
アクセス権 open access
アクセス権URI http://purl.org/coar/access_right/c_abf2
著者 Hoshi, Masayuki

× Hoshi, Masayuki

WEKO 44473

en Hoshi, Masayuki

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Hayatsu, Takaki

× Hayatsu, Takaki

WEKO 44474

en Hayatsu, Takaki

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Okimoto, Mitsuhiro

× Okimoto, Mitsuhiro

WEKO 44475

en Okimoto, Mitsuhiro

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Kodama, Satoshi

× Kodama, Satoshi

WEKO 44476

en Kodama, Satoshi

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著者別名
姓名 星, 雅之
言語 ja
抄録
内容記述タイプ Abstract
内容記述 Treatment of (E)-alk-1-enyldicyclohexylboranes with tributyltin methoxide in the presence of galvinoxyl (1 mol%) at room temperature results in transfer of the alk-1-enyl group from boron to tin to give (E)-alk-1-enyltributylstannanes in a highly stereoselective fashion. Subsequent halodestannylation of (E)-alk-1-enyltributylstannanes is allowed to proceed in a one-pot manner to produce the corresponding (E)-1-iodoalk-1-enes and (E)-1-bromoalk-1-enes in good to high yields, respectively.
書誌情報 Synlett

巻 18, p. 2945-2948, 発行日 2009
DOI
識別子タイプ DOI
関連識別子 http://doi.org/10.1055/s-0029-1218009
権利
権利情報 c Georg Thieme Verlag Stuttgart ? New York
出版者
出版者 Georg Thieme Verlag
著者版フラグ
値 author
出版タイプ
出版タイプ AM
出版タイプResource http://purl.org/coar/version/c_ab4af688f83e57aa
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