{"_buckets": {"deposit": "973347c1-61cf-419e-bf52-ca0695f98d85"}, "_deposit": {"id": "8445", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "8445"}, "status": "published"}, "_oai": {"id": "oai:kitami-it.repo.nii.ac.jp:00008445", "sets": ["1:87"]}, "author_link": ["44871", "44473", "44474", "44475", "44476"], "item_1646810750418": {"attribute_name": "\u51fa\u7248\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_3_biblio_info_186": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2009", "bibliographicIssueDateType": "Issued"}, "bibliographicPageEnd": "2948", "bibliographicPageStart": "2945", "bibliographicVolumeNumber": "18", "bibliographic_titles": [{"bibliographic_title": "Synlett"}]}]}, "item_3_description_184": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "Treatment of (E)-alk-1-enyldicyclohexylboranes with tributyltin methoxide in the presence of galvinoxyl (1 mol%) at room temperature results in transfer of the alk-1-enyl group from boron to tin to give (E)-alk-1-enyltributylstannanes in a highly stereoselective fashion. Subsequent halodestannylation of (E)-alk-1-enyltributylstannanes is allowed to proceed in a one-pot manner to produce the corresponding (E)-1-iodoalk-1-enes and (E)-1-bromoalk-1-enes in good to high yields, respectively.", "subitem_description_type": "Abstract"}]}, "item_3_full_name_183": {"attribute_name": "\u8457\u8005\u5225\u540d", "attribute_value_mlt": [{"nameIdentifiers": [{"nameIdentifier": "44871", "nameIdentifierScheme": "WEKO"}, {"nameIdentifier": "113712", "nameIdentifierScheme": "KAKEN", "nameIdentifierURI": "https://nrid.nii.ac.jp/ja/nrid/1000000113712 "}], "names": [{"name": "\u661f, \u96c5\u4e4b", "nameLang": "ja"}]}]}, "item_3_publisher_212": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "Georg Thieme Verlag"}]}, "item_3_relation_191": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type_id": {"subitem_relation_type_id_text": "http://doi.org/10.1055/s-0029-1218009", "subitem_relation_type_select": "DOI"}}]}, "item_3_rights_192": {"attribute_name": "\u6a29\u5229", "attribute_value_mlt": [{"subitem_rights": "c Georg Thieme Verlag Stuttgart ? New York"}]}, "item_3_select_195": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_3_subject_196": {"attribute_name": "\u65e5\u672c\u5341\u9032\u5206\u985e\u6cd5", "attribute_value_mlt": [{"subitem_subject": "430", "subitem_subject_scheme": "NDC"}]}, "item_access_right": {"attribute_name": "\u30a2\u30af\u30bb\u30b9\u6a29", "attribute_value_mlt": [{"subitem_access_right": "open access", "subitem_access_right_uri": "http://purl.org/coar/access_right/c_abf2"}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Hoshi, Masayuki", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "44473", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Hayatsu, Takaki", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "44474", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Okimoto, Mitsuhiro", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "44475", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Kodama, Satoshi", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "44476", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2017-01-12"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "u07509st.pdf", "filesize": [{"value": "82.0 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_note", "mimetype": "application/pdf", "size": 82000.0, "url": {"label": "u07509st.pdf", "url": "https://kitami-it.repo.nii.ac.jp/record/8445/files/u07509st.pdf"}, "version_id": "4abdd8db-ca30-48c6-ae7c-0c7eb7533dd8"}]}, "item_keyword": {"attribute_name": "\u30ad\u30fc\u30ef\u30fc\u30c9", "attribute_value_mlt": [{"subitem_subject": "transfer", "subitem_subject_scheme": "Other"}, {"subitem_subject": "(E)-alk-1-enyltributylstannane", "subitem_subject_scheme": "Other"}, {"subitem_subject": "(E)-alk-1-enyldicyclohexylborane", "subitem_subject_scheme": "Other"}, {"subitem_subject": "tributyltin methoxide", "subitem_subject_scheme": "Other"}, {"subitem_subject": "halodestannylation", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Transfer of alk-1-enyl group from boron to tin: A highly stereoselective synthesis of (E)-alk-1-enyltributylstannanes", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Transfer of alk-1-enyl group from boron to tin: A highly stereoselective synthesis of (E)-alk-1-enyltributylstannanes", "subitem_title_language": "en"}]}, "item_type_id": "3", "owner": "1", "path": ["1/87"], "permalink_uri": "https://kitami-it.repo.nii.ac.jp/records/8445", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2016-08-31"}, "publish_date": "2016-08-31", "publish_status": "0", "recid": "8445", "relation": {}, "relation_version_is_last": true, "title": ["Transfer of alk-1-enyl group from boron to tin: A highly stereoselective synthesis of (E)-alk-1-enyltributylstannanes"], "weko_shared_id": -1}