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Transfer of alk-1-enyl group from boron to tin: A highly stereoselective synthesis of (E)-alk-1-enyltributylstannanes
https://kitami-it.repo.nii.ac.jp/records/8445
https://kitami-it.repo.nii.ac.jp/records/8445dd85a860-c24f-4f8d-9e02-be2bb5b32939
名前 / ファイル | ライセンス | アクション |
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2016-08-31 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Transfer of alk-1-enyl group from boron to tin: A highly stereoselective synthesis of (E)-alk-1-enyltributylstannanes | |||||
言語 | ||||||
言語 | eng | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | transfer | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | (E)-alk-1-enyltributylstannane | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | (E)-alk-1-enyldicyclohexylborane | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | tributyltin methoxide | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | halodestannylation | |||||
資源タイプ | ||||||
資源 | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
アクセス権 | ||||||
アクセス権 | open access | |||||
アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||
著者 |
Hoshi, Masayuki
× Hoshi, Masayuki× Hayatsu, Takaki× Okimoto, Mitsuhiro× Kodama, Satoshi |
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著者別名 | ||||||
姓名 | 星, 雅之 | |||||
言語 | ja | |||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | Treatment of (E)-alk-1-enyldicyclohexylboranes with tributyltin methoxide in the presence of galvinoxyl (1 mol%) at room temperature results in transfer of the alk-1-enyl group from boron to tin to give (E)-alk-1-enyltributylstannanes in a highly stereoselective fashion. Subsequent halodestannylation of (E)-alk-1-enyltributylstannanes is allowed to proceed in a one-pot manner to produce the corresponding (E)-1-iodoalk-1-enes and (E)-1-bromoalk-1-enes in good to high yields, respectively. | |||||
書誌情報 |
Synlett 巻 18, p. 2945-2948, 発行日 2009 |
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DOI | ||||||
識別子タイプ | DOI | |||||
関連識別子 | http://doi.org/10.1055/s-0029-1218009 | |||||
権利 | ||||||
権利情報 | c Georg Thieme Verlag Stuttgart ? New York | |||||
出版者 | ||||||
出版者 | Georg Thieme Verlag | |||||
著者版フラグ | ||||||
値 | author | |||||
出版タイプ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa |