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Preparation of Optically Active δ-Tri- and δ-Tetradecalactones by a Combination of Novozym 435-catalyzed Enantioselective Methanolysis and Amidation
https://kitami-it.repo.nii.ac.jp/records/8108
https://kitami-it.repo.nii.ac.jp/records/8108b9ef43dc-eff3-4b30-aef5-a40d18f3ec4f
名前 / ファイル | ライセンス | アクション |
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2015_Preparation of optically active δ-tri- and δ-tetradecalactones by a combination of Novozym 435-catalyzed enantioselective methanolysis and amidation.pdf (455.5 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2016-03-18 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Preparation of Optically Active δ-Tri- and δ-Tetradecalactones by a Combination of Novozym 435-catalyzed Enantioselective Methanolysis and Amidation | |||||
言語 | ||||||
言語 | eng | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | δ-tridecalactone | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | δ-tetradecalactone | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | lipase-catalyzed kinetic resolution | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | methanolysis | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | amidation | |||||
資源タイプ | ||||||
資源 | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
アクセス権 | ||||||
アクセス権 | open access | |||||
アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||
著者 |
Shimotori, Yasutaka
× Shimotori, Yasutaka× Hoshi, Masayuki× Okabe, Hayato× Miyakoshi, Tetsuo |
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著者別名 | ||||||
姓名 | 霜鳥, 慈岳 | |||||
言語 | ja | |||||
著者別名 | ||||||
姓名 | 星, 雅之 | |||||
言語 | ja | |||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | A combination of Novozym 435-catalyzed methanolysis and amidation using racemic N-methyl-5-acetoxytridecan- and tetradecanamides as a substrate proceeded in good enantioselectivity to afford the corresponding (R)-N-methyl-5-acetoxyalkanamides, (S)-N-methyl-5-hydroxyalkanamides, and (S)-N-cyclohexyl-5-hydroxyalkanamides. Both enantiomers of δ-tri- and δ-tetradecalactones were synthesized in over 90% enantiomeric excesses from the corresponding (R)- or (S)-alkanamides. Addition of cyclohexylamine to Novozym 435-catalyzed methanolysis shortened 24-hour reaction time to reach about 50% conversion. Enantiomers of optically active δ-tri- and δ-tetradecalactones had different odors and thresholds | |||||
書誌情報 |
Journal of Oleo Science 巻 64, 号 11, p. 1213-1226, 発行日 2015 |
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DOI | ||||||
識別子タイプ | DOI | |||||
関連識別子 | http://doi.org/10.5650/jos.ess15120 | |||||
権利 | ||||||
権利情報 | c 2015 by Japan Oil Chemists' Society | |||||
出版者 | ||||||
出版者 | Japan Oil Chemists Society | |||||
著者版フラグ | ||||||
値 | publisher | |||||
出版タイプ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 |