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Preparation of Optically Active δ-Tri- and δ-Tetradecalactones by a Combination of Novozym 435-catalyzed Enantioselective Methanolysis and Amidation
https://kitami-it.repo.nii.ac.jp/records/8108
https://kitami-it.repo.nii.ac.jp/records/8108b9ef43dc-eff3-4b30-aef5-a40d18f3ec4f
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
2015_Preparation of optically active δ-tri- and δ-tetradecalactones by a combination of Novozym 435-catalyzed enantioselective methanolysis and amidation.pdf (455.5 kB)
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||
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| 公開日 | 2016-03-18 | |||||
| タイトル | ||||||
| タイトル | Preparation of Optically Active δ-Tri- and δ-Tetradecalactones by a Combination of Novozym 435-catalyzed Enantioselective Methanolysis and Amidation | |||||
| 言語 | en | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | δ-tridecalactone | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | δ-tetradecalactone | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | lipase-catalyzed kinetic resolution | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | methanolysis | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | amidation | |||||
| 資源タイプ | ||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
| 資源タイプ | journal article | |||||
| アクセス権 | ||||||
| アクセス権 | open access | |||||
| アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||
| 著者 |
Shimotori, Yasutaka
× Shimotori, Yasutaka× Hoshi, Masayuki× Okabe, Hayato× Miyakoshi, Tetsuo |
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| 著者別名 | ||||||
| 識別子Scheme | WEKO | |||||
| 識別子 | 42341 | |||||
| 姓名 | 霜鳥, 慈岳 | |||||
| 言語 | ja | |||||
| 著者別名 | ||||||
| 識別子Scheme | WEKO | |||||
| 識別子 | 44871 | |||||
| 識別子Scheme | KAKEN | |||||
| 識別子URI | https://nrid.nii.ac.jp/ja/nrid/1000000113712 | |||||
| 識別子 | 113712 | |||||
| 姓名 | 星, 雅之 | |||||
| 言語 | ja | |||||
| 抄録 | ||||||
| 内容記述タイプ | Abstract | |||||
| 内容記述 | A combination of Novozym 435-catalyzed methanolysis and amidation using racemic N-methyl-5-acetoxytridecan- and tetradecanamides as a substrate proceeded in good enantioselectivity to afford the corresponding (R)-N-methyl-5-acetoxyalkanamides, (S)-N-methyl-5-hydroxyalkanamides, and (S)-N-cyclohexyl-5-hydroxyalkanamides. Both enantiomers of δ-tri- and δ-tetradecalactones were synthesized in over 90% enantiomeric excesses from the corresponding (R)- or (S)-alkanamides. Addition of cyclohexylamine to Novozym 435-catalyzed methanolysis shortened 24-hour reaction time to reach about 50% conversion. Enantiomers of optically active δ-tri- and δ-tetradecalactones had different odors and thresholds | |||||
| 書誌情報 |
Journal of Oleo Science 巻 64, 号 11, p. 1213-1226, 発行日 2015 |
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| DOI | ||||||
| 識別子タイプ | DOI | |||||
| 関連識別子 | http://doi.org/10.5650/jos.ess15120 | |||||
| 権利 | ||||||
| 権利情報 | c 2015 by Japan Oil Chemists' Society | |||||
| 出版者 | ||||||
| 出版者 | Japan Oil Chemists Society | |||||
| 著者版フラグ | ||||||
| 値 | publisher | |||||
| 出版タイプ | ||||||
| 出版タイプ | VoR | |||||
| 出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
