{"created":"2021-03-01T06:00:34.096228+00:00","id":8108,"links":{},"metadata":{"_buckets":{"deposit":"d8cd243e-006b-4f70-8cb9-a0fd5a5782c9"},"_deposit":{"id":"8108","owners":[],"pid":{"revision_id":0,"type":"depid","value":"8108"},"status":"published"},"_oai":{"id":"oai:kitami-it.repo.nii.ac.jp:00008108","sets":["1:87"]},"author_link":["42341","44871","42337","42338","42339","42340"],"item_1646810750418":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_3_biblio_info_186":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2015","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"11","bibliographicPageEnd":"1226","bibliographicPageStart":"1213","bibliographicVolumeNumber":"64","bibliographic_titles":[{"bibliographic_title":"Journal of Oleo Science"}]}]},"item_3_description_184":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"A combination of Novozym 435-catalyzed methanolysis and amidation using racemic N-methyl-5-acetoxytridecan- and tetradecanamides as a substrate proceeded in good enantioselectivity to afford the corresponding (R)-N-methyl-5-acetoxyalkanamides, (S)-N-methyl-5-hydroxyalkanamides, and (S)-N-cyclohexyl-5-hydroxyalkanamides. Both enantiomers of δ-tri- and δ-tetradecalactones were synthesized in over 90% enantiomeric excesses from the corresponding (R)- or (S)-alkanamides. Addition of cyclohexylamine to Novozym 435-catalyzed methanolysis shortened 24-hour reaction time to reach about 50% conversion. Enantiomers of optically active δ-tri- and δ-tetradecalactones had different odors and thresholds","subitem_description_type":"Abstract"}]},"item_3_full_name_183":{"attribute_name":"著者別名","attribute_value_mlt":[{"nameIdentifiers":[{"nameIdentifier":"42341","nameIdentifierScheme":"WEKO"}],"names":[{"name":"霜鳥, 慈岳","nameLang":"ja"}]},{"nameIdentifiers":[{"nameIdentifier":"44871","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"113712","nameIdentifierScheme":"KAKEN","nameIdentifierURI":"https://nrid.nii.ac.jp/ja/nrid/1000000113712 "}],"names":[{"name":"星, 雅之","nameLang":"ja"}]}]},"item_3_publisher_212":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Japan Oil Chemists Society"}]},"item_3_relation_191":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"http://doi.org/10.5650/jos.ess15120","subitem_relation_type_select":"DOI"}}]},"item_3_rights_192":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"c 2015 by Japan Oil Chemists' Society"}]},"item_3_select_195":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"publisher"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Shimotori, Yasutaka","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"42337","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Hoshi, Masayuki","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"42338","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Okabe, Hayato","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"42339","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Miyakoshi, Tetsuo","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"42340","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2016-11-22"}],"displaytype":"detail","filename":"2015_Preparation of optically active δ-tri- and δ-tetradecalactones by a combination of Novozym 435-catalyzed enantioselective methanolysis and amidation.pdf","filesize":[{"value":"455.5 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"2015_Preparation of optically active δ-tri- and δ-tetradecalactones by a combination of Novozym 435-catalyzed enantioselective methanolysis and amidation.pdf","url":"https://kitami-it.repo.nii.ac.jp/record/8108/files/2015_Preparation of optically active δ-tri- and δ-tetradecalactones by a combination of Novozym 435-catalyzed enantioselective methanolysis and amidation.pdf"},"version_id":"bd10c1b9-e076-47f3-8894-d13cc69a42a2"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"δ-tridecalactone","subitem_subject_scheme":"Other"},{"subitem_subject":"δ-tetradecalactone","subitem_subject_scheme":"Other"},{"subitem_subject":"lipase-catalyzed kinetic resolution","subitem_subject_scheme":"Other"},{"subitem_subject":"methanolysis","subitem_subject_scheme":"Other"},{"subitem_subject":"amidation","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Preparation of Optically Active δ-Tri- and δ-Tetradecalactones by a Combination of Novozym 435-catalyzed Enantioselective Methanolysis and Amidation","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Preparation of Optically Active δ-Tri- and δ-Tetradecalactones by a Combination of Novozym 435-catalyzed Enantioselective Methanolysis and Amidation","subitem_title_language":"en"}]},"item_type_id":"3","owner":"1","path":["87"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2016-03-18"},"publish_date":"2016-03-18","publish_status":"0","recid":"8108","relation_version_is_last":true,"title":["Preparation of Optically Active δ-Tri- and δ-Tetradecalactones by a Combination of Novozym 435-catalyzed Enantioselective Methanolysis and Amidation"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2024-06-03T02:12:08.694867+00:00"}