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  1. 学術雑誌掲載済論文
  2. 洋雑誌

Combination of Novozym 435-catalyzed enantioselective hydrolysis and amidation for the preparation of optically active δ-hexadecalactone

https://kitami-it.repo.nii.ac.jp/records/7977
486c9330-4359-4169-9bbd-3658c3f34140
名前 / ファイル ライセンス アクション
2015_Combination 2015_Combination of Novozym 435-catalyzed enantioselective hydrolysis and amidation for the preparation of optically active δ-hexadecalactone.pdf (676.2 kB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2015-09-09
タイトル
言語 en
タイトル Combination of Novozym 435-catalyzed enantioselective hydrolysis and amidation for the preparation of optically active δ-hexadecalactone
言語
言語 eng
キーワード
主題Scheme Other
主題 δ-hexadecalactone
キーワード
主題Scheme Other
主題 lipase-catalyzed resolution
キーワード
主題Scheme Other
主題 hydrolysis, amidation
資源タイプ
資源 http://purl.org/coar/resource_type/c_6501
タイプ journal article
アクセス権
アクセス権 open access
アクセス権URI http://purl.org/coar/access_right/c_abf2
著者 Shimotori, Yasutaka

× Shimotori, Yasutaka

WEKO 41397

en Shimotori, Yasutaka

Search repository
Hoshi, Masayuki

× Hoshi, Masayuki

WEKO 41398

en Hoshi, Masayuki

Search repository
Miyakoshi, Tetsuo

× Miyakoshi, Tetsuo

WEKO 41399

en Miyakoshi, Tetsuo

Search repository
著者別名
姓名
姓名 霜鳥, 慈岳
言語 ja
著者別名
姓名
姓名 星, 雅之
言語 ja
抄録
内容記述タイプ Abstract
内容記述 A new enzymatic method for synthesis of enantiomerically enriched δ-hexadecalactone (3) based on the enzymatic kinetic resolution of N-methyl-5-acetoxyhexadecanamide (1) is described. A combination of lipase-catalyzed hydrolysis and amidation improved enantioselectivity. Lipase-catalyzed amidation was also investigated. Detailed screening of solvents and additive amines was performed. The addition of cyclohexylamine to lipase-catalyzed hydrolysis afforded the best results to give both enantiomers of 3 with more than 90% enantiomeric excess.
書誌情報 Journal of Oleo Science 64(5), 561-575

巻 64, 号 5, p. 561-575, 発行日 2015
DOI
関連識別子
識別子タイプ DOI
関連識別子 http://doi.org/10.5650/jos.ess14232
権利
権利情報 c 2015 by Japan Oil Chemists' Society
出版者
出版者 Japan Oil Chemists' Society (公益社団法人日本油化学会)
著者版フラグ
値 publisher
出版タイプ
出版タイプ VoR
出版タイプResource http://purl.org/coar/version/c_970fb48d4fbd8a85
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