{"_buckets": {"deposit": "08732165-cd57-4565-a5da-708ff2d9014c"}, "_deposit": {"id": "7977", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "7977"}, "status": "published"}, "_oai": {"id": "oai:kitami-it.repo.nii.ac.jp:00007977"}, "item_3_biblio_info_186": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2015", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "5", "bibliographicPageEnd": "575", "bibliographicPageStart": "561", "bibliographicVolumeNumber": "64", "bibliographic_titles": [{"bibliographic_title": "Journal of Oleo Science  64(5), 561-575"}]}]}, "item_3_description_184": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "A new enzymatic method for synthesis of enantiomerically enriched \u03b4-hexadecalactone (3) based on the enzymatic kinetic resolution of N-methyl-5-acetoxyhexadecanamide (1) is described. A combination of lipase-catalyzed hydrolysis and amidation improved enantioselectivity. Lipase-catalyzed amidation was also investigated. Detailed screening of solvents and additive amines was performed. The addition of cyclohexylamine to lipase-catalyzed hydrolysis afforded the best results to give both enantiomers of 3 with more than 90% enantiomeric excess.", "subitem_description_type": "Abstract"}]}, "item_3_full_name_183": {"attribute_name": "\u8457\u8005\u5225\u540d", "attribute_value_mlt": [{"nameIdentifiers": [{"nameIdentifier": "41400", "nameIdentifierScheme": "WEKO"}], "names": [{"name": "\u971c\u9ce5, \u6148\u5cb3"}]}, {"nameIdentifiers": [{"nameIdentifier": "44871", "nameIdentifierScheme": "WEKO"}, {"nameIdentifier": "1000000113712 ", "nameIdentifierScheme": "NRID", "nameIdentifierURI": "http://rns.nii.ac.jp/d/nr/1000000113712 "}], "names": [{"name": "\u661f, \u96c5\u4e4b"}]}]}, "item_3_publisher_212": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "Japan Oil Chemists\u0027 Society (\u516c\u76ca\u793e\u56e3\u6cd5\u4eba\u65e5\u672c\u6cb9\u5316\u5b66\u4f1a)"}]}, "item_3_relation_191": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type_id": {"subitem_relation_type_id_text": "http://doi.org/10.5650/jos.ess14232", "subitem_relation_type_select": "DOI"}}]}, "item_3_rights_192": {"attribute_name": "\u6a29\u5229", "attribute_value_mlt": [{"subitem_rights": "c 2015 by Japan Oil Chemists\u0027 Society"}]}, "item_3_select_195": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "publisher"}]}, "item_3_subject_196": {"attribute_name": "\u65e5\u672c\u5341\u9032\u5206\u985e\u6cd5", "attribute_value_mlt": [{"subitem_subject": "501", "subitem_subject_scheme": "NDC"}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Shimotori, Yasutaka"}], "nameIdentifiers": [{"nameIdentifier": "41397", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Hoshi, Masayuki"}], "nameIdentifiers": [{"nameIdentifier": "41398", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Miyakoshi, Tetsuo"}], "nameIdentifiers": [{"nameIdentifier": "41399", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2016-11-22"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "2015_Combination of Novozym 435-catalyzed enantioselective hydrolysis and amidation for the preparation of optically active \u03b4-hexadecalactone.pdf", "filesize": [{"value": "676.2 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 676200.0, "url": {"label": "2015_Combination of Novozym 435-catalyzed enantioselective hydrolysis and amidation for the preparation of optically active \u03b4-hexadecalactone.pdf", "url": "https://kitami-it.repo.nii.ac.jp/record/7977/files/2015_Combination of Novozym 435-catalyzed enantioselective hydrolysis and amidation for the preparation of optically active \u03b4-hexadecalactone.pdf"}, "version_id": "ecf12fe8-47ec-464a-bc55-1389e5af1b36"}]}, "item_keyword": {"attribute_name": "\u30ad\u30fc\u30ef\u30fc\u30c9", "attribute_value_mlt": [{"subitem_subject": "\u03b4-hexadecalactone", "subitem_subject_scheme": "Other"}, {"subitem_subject": "lipase-catalyzed resolution", "subitem_subject_scheme": "Other"}, {"subitem_subject": "hydrolysis, amidation", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Combination of Novozym 435-catalyzed enantioselective hydrolysis and amidation for the preparation of optically active \u03b4-hexadecalactone", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Combination of Novozym 435-catalyzed enantioselective hydrolysis and amidation for the preparation of optically active \u03b4-hexadecalactone"}]}, "item_type_id": "3", "owner": "1", "path": ["1"], "permalink_uri": "https://kitami-it.repo.nii.ac.jp/records/7977", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_value": "2015-09-09"}, "publish_date": "2015-09-09", "publish_status": "0", "recid": "7977", "relation": {}, "relation_version_is_last": true, "title": ["Combination of Novozym 435-catalyzed enantioselective hydrolysis and amidation for the preparation of optically active \u03b4-hexadecalactone"], "weko_shared_id": 3}