{"_buckets": {"deposit": "08732165-cd57-4565-a5da-708ff2d9014c"}, "_deposit": {"id": "7977", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "7977"}, "status": "published"}, "_oai": {"id": "oai:kitami-it.repo.nii.ac.jp:00007977", "sets": ["87"]}, "author_link": ["41400", "44871", "41397", "41398", "41399"], "item_1646810750418": {"attribute_name": "出版タイプ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_970fb48d4fbd8a85", "subitem_version_type": "VoR"}]}, "item_3_biblio_info_186": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2015", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "5", "bibliographicPageEnd": "575", "bibliographicPageStart": "561", "bibliographicVolumeNumber": "64", "bibliographic_titles": [{"bibliographic_title": "Journal of Oleo Science  64(5), 561-575"}]}]}, "item_3_description_184": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "A new enzymatic method for synthesis of enantiomerically enriched δ-hexadecalactone (3) based on the enzymatic kinetic resolution of N-methyl-5-acetoxyhexadecanamide (1) is described. A combination of lipase-catalyzed hydrolysis and amidation improved enantioselectivity. Lipase-catalyzed amidation was also investigated. Detailed screening of solvents and additive amines was performed. The addition of cyclohexylamine to lipase-catalyzed hydrolysis afforded the best results to give both enantiomers of 3 with more than 90% enantiomeric excess.", "subitem_description_type": "Abstract"}]}, "item_3_full_name_183": {"attribute_name": "著者別名", "attribute_value_mlt": [{"nameIdentifiers": [{"nameIdentifier": "41400", "nameIdentifierScheme": "WEKO"}], "names": [{"name": "霜鳥, 慈岳", "nameLang": "ja"}]}, {"nameIdentifiers": [{"nameIdentifier": "44871", "nameIdentifierScheme": "WEKO"}, {"nameIdentifier": "113712", "nameIdentifierScheme": "KAKEN", "nameIdentifierURI": "https://nrid.nii.ac.jp/ja/nrid/1000000113712 "}], "names": [{"name": "星, 雅之", "nameLang": "ja"}]}]}, "item_3_publisher_212": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "Japan Oil Chemists\u0027 Society (公益社団法人日本油化学会)"}]}, "item_3_relation_191": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type_id": {"subitem_relation_type_id_text": "http://doi.org/10.5650/jos.ess14232", "subitem_relation_type_select": "DOI"}}]}, "item_3_rights_192": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": "c 2015 by Japan Oil Chemists\u0027 Society"}]}, "item_3_select_195": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_select_item": "publisher"}]}, "item_3_subject_196": {"attribute_name": "日本十進分類法", "attribute_value_mlt": [{"subitem_subject": "501", "subitem_subject_scheme": "NDC"}]}, "item_access_right": {"attribute_name": "アクセス権", "attribute_value_mlt": [{"subitem_access_right": "open access", "subitem_access_right_uri": "http://purl.org/coar/access_right/c_abf2"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Shimotori, Yasutaka", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "41397", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Hoshi, Masayuki", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "41398", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Miyakoshi, Tetsuo", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "41399", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2016-11-22"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "2015_Combination of Novozym 435-catalyzed enantioselective hydrolysis and amidation for the preparation of optically active δ-hexadecalactone.pdf", "filesize": [{"value": "676.2 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_note", "mimetype": "application/pdf", "size": 676200.0, "url": {"label": "2015_Combination of Novozym 435-catalyzed enantioselective hydrolysis and amidation for the preparation of optically active δ-hexadecalactone.pdf", "url": "https://kitami-it.repo.nii.ac.jp/record/7977/files/2015_Combination of Novozym 435-catalyzed enantioselective hydrolysis and amidation for the preparation of optically active δ-hexadecalactone.pdf"}, "version_id": "ecf12fe8-47ec-464a-bc55-1389e5af1b36"}]}, "item_keyword": {"attribute_name": "キーワード", "attribute_value_mlt": [{"subitem_subject": "δ-hexadecalactone", "subitem_subject_scheme": "Other"}, {"subitem_subject": "lipase-catalyzed resolution", "subitem_subject_scheme": "Other"}, {"subitem_subject": "hydrolysis, amidation", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Combination of Novozym 435-catalyzed enantioselective hydrolysis and amidation for the preparation of optically active δ-hexadecalactone", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Combination of Novozym 435-catalyzed enantioselective hydrolysis and amidation for the preparation of optically active δ-hexadecalactone", "subitem_title_language": "en"}]}, "item_type_id": "3", "owner": "1", "path": ["87"], "permalink_uri": "https://kitami-it.repo.nii.ac.jp/records/7977", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2015-09-09"}, "publish_date": "2015-09-09", "publish_status": "0", "recid": "7977", "relation": {}, "relation_version_is_last": true, "title": ["Combination of Novozym 435-catalyzed enantioselective hydrolysis and amidation for the preparation of optically active δ-hexadecalactone"], "weko_shared_id": -1}