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Combination of Novozym 435-catalyzed enantioselective hydrolysis and amidation for the preparation of optically active δ-hexadecalactone
https://kitami-it.repo.nii.ac.jp/records/7977
https://kitami-it.repo.nii.ac.jp/records/7977486c9330-4359-4169-9bbd-3658c3f34140
名前 / ファイル | ライセンス | アクション |
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2015-09-09 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Combination of Novozym 435-catalyzed enantioselective hydrolysis and amidation for the preparation of optically active δ-hexadecalactone | |||||
言語 | ||||||
言語 | eng | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | δ-hexadecalactone | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | lipase-catalyzed resolution | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | hydrolysis, amidation | |||||
資源タイプ | ||||||
資源 | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
アクセス権 | ||||||
アクセス権 | open access | |||||
アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||
著者 |
Shimotori, Yasutaka
× Shimotori, Yasutaka× Hoshi, Masayuki× Miyakoshi, Tetsuo |
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著者別名 | ||||||
姓名 | 霜鳥, 慈岳 | |||||
言語 | ja | |||||
著者別名 | ||||||
姓名 | 星, 雅之 | |||||
言語 | ja | |||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | A new enzymatic method for synthesis of enantiomerically enriched δ-hexadecalactone (3) based on the enzymatic kinetic resolution of N-methyl-5-acetoxyhexadecanamide (1) is described. A combination of lipase-catalyzed hydrolysis and amidation improved enantioselectivity. Lipase-catalyzed amidation was also investigated. Detailed screening of solvents and additive amines was performed. The addition of cyclohexylamine to lipase-catalyzed hydrolysis afforded the best results to give both enantiomers of 3 with more than 90% enantiomeric excess. | |||||
書誌情報 |
Journal of Oleo Science 64(5), 561-575 巻 64, 号 5, p. 561-575, 発行日 2015 |
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DOI | ||||||
識別子タイプ | DOI | |||||
関連識別子 | http://doi.org/10.5650/jos.ess14232 | |||||
権利 | ||||||
権利情報 | c 2015 by Japan Oil Chemists' Society | |||||
出版者 | ||||||
出版者 | Japan Oil Chemists' Society (公益社団法人日本油化学会) | |||||
著者版フラグ | ||||||
値 | publisher | |||||
出版タイプ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 |