| Item type |
学術雑誌論文 / Journal Article(1) |
| 公開日 |
2015-08-19 |
| タイトル |
|
|
タイトル |
Dye-sensitized Solar Cells with New One-Dimensional Halide-Bridged Cu(I)-Ni(II) Heterometal Coordination Polymers Containing Hexamethylene Dithiocarbamate Ligand |
|
言語 |
en |
| 言語 |
|
|
言語 |
eng |
| キーワード |
|
|
主題Scheme |
Other |
|
主題 |
coordination polymer |
| キーワード |
|
|
主題Scheme |
Other |
|
主題 |
crystal structure |
| キーワード |
|
|
主題Scheme |
Other |
|
主題 |
electric-conductivity |
| キーワード |
|
|
主題Scheme |
Other |
|
主題 |
dye-sensitized solar cell |
| 資源タイプ |
|
|
資源 |
http://purl.org/coar/resource_type/c_6501 |
|
タイプ |
journal article |
| アクセス権 |
|
|
アクセス権 |
open access |
|
アクセス権URI |
http://purl.org/coar/access_right/c_abf2 |
| 著者 |
Okubo, Takashi
Tanaka, Naoya
Anma, Haruho
Kim, Kyung Ho
Maekawa, Masahiko
Kuroda-Sowa, Takayoshi
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| 著者別名 |
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識別子Scheme |
WEKO |
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識別子 |
44878 |
|
|
識別子Scheme |
KAKEN |
|
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識別子URI |
https://nrid.nii.ac.jp/ja/nrid/1000070608471 |
|
|
識別子 |
70608471 |
|
|
姓名 |
金, 敬鎬 |
|
|
言語 |
ja |
| 抄録 |
|
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内容記述タイプ |
Abstract |
|
内容記述 |
One-dimensional (1D) halide-bridged Cu(I)–Ni(II) heterometal coordination polymers containing a hexamethylene dithiocarbamate (Hm-dtc) ligand have been synthesized and crystallographically characterized. The highest occupied molecular orbital (HOMO) and lowest unoccupied molecular orbital (LUMO) levels of the coordination polymers were estimated using UV-Vis-NIR and photoelectron spectroscopies, and it was revealed that these coordination polymers have appropriate HOMO levels for use as dye sensitizers. Direct-current electrical conductivity measurements and impedance measurements indicated that these 1D Cu(I)–Ni(II) heterometal coordination polymers were insulators ( σ 300K < 10 ？12 S cm ？1). In addition, the coordination polymers were used as sensitizing materials in dye-sensitized solar cells (DSSCs). DSSCs with 1D Cu(I)–Ni(II) heterometal coordination polymers showed lower performances than those with 1D halide-bridged Cu(I)–Cu(II) mixed-valence coordination polymers. |
| 内容記述 |
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|
内容記述タイプ |
Other |
|
内容記述 |
Creative Commons Attribution license
(http://creativecommons.org/licenses/by/3.0/) |
| 書誌情報 |
Polymers
巻 4,
p. 1613-1626,
発行日 2012
|
| DOI |
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|
識別子タイプ |
DOI |
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関連識別子 |
http://doi.org/10.3390/polym4031613 |
| 出版者 |
|
|
出版者 |
MDPI |
|
言語 |
en |
| 著者版フラグ |
|
|
言語 |
en |
|
値 |
publisher |
| 出版タイプ |
|
|
出版タイプ |
VoR |
|
出版タイプResource |
http://purl.org/coar/version/c_970fb48d4fbd8a85 |
No252.pdf (914.3 kB)
