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Dye-sensitized Solar Cells with New One-Dimensional Halide-Bridged Cu(I)-Ni(II) Heterometal Coordination Polymers Containing Hexamethylene Dithiocarbamate Ligand
https://kitami-it.repo.nii.ac.jp/records/7904
https://kitami-it.repo.nii.ac.jp/records/7904a9cc7a63-3ff5-4d0d-9294-7bf32955199b
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
No252.pdf (914.3 kB)
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||
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| 公開日 | 2015-08-19 | |||||
| タイトル | ||||||
| タイトル | Dye-sensitized Solar Cells with New One-Dimensional Halide-Bridged Cu(I)-Ni(II) Heterometal Coordination Polymers Containing Hexamethylene Dithiocarbamate Ligand | |||||
| 言語 | en | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | coordination polymer | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | crystal structure | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | electric-conductivity | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | dye-sensitized solar cell | |||||
| 資源タイプ | ||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
| 資源タイプ | journal article | |||||
| アクセス権 | ||||||
| アクセス権 | open access | |||||
| アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||
| 著者 |
Okubo, Takashi
× Okubo, Takashi× Tanaka, Naoya× Anma, Haruho× Kim, Kyung Ho× Maekawa, Masahiko× Kuroda-Sowa, Takayoshi |
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| 著者別名 | ||||||
| 識別子Scheme | WEKO | |||||
| 識別子 | 44878 | |||||
| 識別子Scheme | KAKEN | |||||
| 識別子URI | https://nrid.nii.ac.jp/ja/nrid/1000070608471 | |||||
| 識別子 | 70608471 | |||||
| 姓名 | 金, 敬鎬 | |||||
| 言語 | ja | |||||
| 抄録 | ||||||
| 内容記述タイプ | Abstract | |||||
| 内容記述 | One-dimensional (1D) halide-bridged Cu(I)–Ni(II) heterometal coordination polymers containing a hexamethylene dithiocarbamate (Hm-dtc) ligand have been synthesized and crystallographically characterized. The highest occupied molecular orbital (HOMO) and lowest unoccupied molecular orbital (LUMO) levels of the coordination polymers were estimated using UV-Vis-NIR and photoelectron spectroscopies, and it was revealed that these coordination polymers have appropriate HOMO levels for use as dye sensitizers. Direct-current electrical conductivity measurements and impedance measurements indicated that these 1D Cu(I)–Ni(II) heterometal coordination polymers were insulators ( σ 300K < 10 ？12 S cm ？1). In addition, the coordination polymers were used as sensitizing materials in dye-sensitized solar cells (DSSCs). DSSCs with 1D Cu(I)–Ni(II) heterometal coordination polymers showed lower performances than those with 1D halide-bridged Cu(I)–Cu(II) mixed-valence coordination polymers. | |||||
| 内容記述 | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/) |
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| 書誌情報 |
Polymers 巻 4, p. 1613-1626, 発行日 2012 |
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| DOI | ||||||
| 識別子タイプ | DOI | |||||
| 関連識別子 | http://doi.org/10.3390/polym4031613 | |||||
| 出版者 | ||||||
| 出版者 | MDPI | |||||
| 著者版フラグ | ||||||
| 値 | publisher | |||||
| 出版タイプ | ||||||
| 出版タイプ | VoR | |||||
| 出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
