{"_buckets": {"deposit": "9a3e566d-5733-450a-ab55-71eae3232621"}, "_deposit": {"id": "7904", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "7904"}, "status": "published"}, "_oai": {"id": "oai:kitami-it.repo.nii.ac.jp:00007904"}, "item_3_biblio_info_186": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2012", "bibliographicIssueDateType": "Issued"}, "bibliographicPageEnd": "1626", "bibliographicPageStart": "1613", "bibliographicVolumeNumber": "4", "bibliographic_titles": [{"bibliographic_title": "Polymers"}]}]}, "item_3_description_184": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "One-dimensional (1D) halide-bridged Cu(I)\u2013Ni(II) heterometal coordination polymers containing a hexamethylene dithiocarbamate (Hm-dtc) ligand have been synthesized and crystallographically characterized. The highest occupied molecular orbital (HOMO) and lowest unoccupied molecular orbital (LUMO) levels of the coordination polymers were estimated using UV-Vis-NIR and photoelectron spectroscopies, and it was revealed that these coordination polymers have appropriate HOMO levels for use as dye sensitizers. Direct-current electrical conductivity measurements and impedance measurements indicated that these 1D Cu(I)\u2013Ni(II) heterometal coordination polymers were insulators ( \u03c3 300K \u003c 10 \uff1f12 S cm \uff1f1). In addition, the coordination polymers were used as sensitizing materials in dye-sensitized solar cells (DSSCs). DSSCs with 1D Cu(I)\u2013Ni(II) heterometal coordination polymers showed lower performances than those with 1D halide-bridged Cu(I)\u2013Cu(II) mixed-valence coordination polymers.", "subitem_description_type": "Abstract"}]}, "item_3_description_185": {"attribute_name": "\u5185\u5bb9\u8a18\u8ff0", "attribute_value_mlt": [{"subitem_description": "Creative Commons Attribution license\n(http://creativecommons.org/licenses/by/3.0/)", "subitem_description_type": "Other"}]}, "item_3_full_name_183": {"attribute_name": "\u8457\u8005\u5225\u540d", "attribute_value_mlt": [{"nameIdentifiers": [{"nameIdentifier": "44878", "nameIdentifierScheme": "WEKO"}, {"nameIdentifier": "1000070608471 ", "nameIdentifierScheme": "NRID", "nameIdentifierURI": "http://rns.nii.ac.jp/d/nr/1000070608471 "}], "names": [{"name": "\u91d1, \u656c\u93ac"}]}]}, "item_3_publisher_212": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "MDPI"}]}, "item_3_relation_191": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type_id": {"subitem_relation_type_id_text": "http://doi.org/10.3390/polym4031613", "subitem_relation_type_select": "DOI"}}]}, "item_3_select_195": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "publisher"}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Okubo, Takashi"}], "nameIdentifiers": [{"nameIdentifier": "40848", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Tanaka, Naoya"}], "nameIdentifiers": [{"nameIdentifier": "40849", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Anma, Haruho"}], "nameIdentifiers": [{"nameIdentifier": "40850", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Kim, Kyung Ho"}], "nameIdentifiers": [{"nameIdentifier": "40851", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Maekawa, Masahiko"}], "nameIdentifiers": [{"nameIdentifier": "40852", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Kuroda-Sowa, Takayoshi"}], "nameIdentifiers": [{"nameIdentifier": "40853", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2016-11-22"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "No252.pdf", "filesize": [{"value": "914.3 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 914300.0, "url": {"label": "No252.pdf", "url": "https://kitami-it.repo.nii.ac.jp/record/7904/files/No252.pdf"}, "version_id": "8d5f64aa-19c2-4071-8308-2496d97ab2e0"}]}, "item_keyword": {"attribute_name": "\u30ad\u30fc\u30ef\u30fc\u30c9", "attribute_value_mlt": [{"subitem_subject": "coordination polymer", "subitem_subject_scheme": "Other"}, {"subitem_subject": "crystal structure", "subitem_subject_scheme": "Other"}, {"subitem_subject": "electric-conductivity", "subitem_subject_scheme": "Other"}, {"subitem_subject": "dye-sensitized solar cell", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Dye-sensitized Solar Cells with New One-Dimensional Halide-Bridged Cu(I)-Ni(II) Heterometal Coordination Polymers Containing Hexamethylene Dithiocarbamate Ligand", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Dye-sensitized Solar Cells with New One-Dimensional Halide-Bridged Cu(I)-Ni(II) Heterometal Coordination Polymers Containing Hexamethylene Dithiocarbamate Ligand"}]}, "item_type_id": "3", "owner": "1", "path": ["1"], "permalink_uri": "https://kitami-it.repo.nii.ac.jp/records/7904", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_value": "2015-08-19"}, "publish_date": "2015-08-19", "publish_status": "0", "recid": "7904", "relation": {}, "relation_version_is_last": true, "title": ["Dye-sensitized Solar Cells with New One-Dimensional Halide-Bridged Cu(I)-Ni(II) Heterometal Coordination Polymers Containing Hexamethylene Dithiocarbamate Ligand"], "weko_shared_id": 3}