{"created":"2021-03-01T06:00:21.774022+00:00","id":7904,"links":{},"metadata":{"_buckets":{"deposit":"9a3e566d-5733-450a-ab55-71eae3232621"},"_deposit":{"id":"7904","owners":[],"pid":{"revision_id":0,"type":"depid","value":"7904"},"status":"published"},"_oai":{"id":"oai:kitami-it.repo.nii.ac.jp:00007904","sets":["1:87"]},"author_link":["44878","40848","40849","40850","40851","40852","40853"],"item_1646810750418":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_3_biblio_info_186":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2012","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"1626","bibliographicPageStart":"1613","bibliographicVolumeNumber":"4","bibliographic_titles":[{"bibliographic_title":"Polymers"}]}]},"item_3_description_184":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"One-dimensional (1D) halide-bridged Cu(I)–Ni(II) heterometal coordination polymers containing a hexamethylene dithiocarbamate (Hm-dtc) ligand have been synthesized and crystallographically characterized. The highest occupied molecular orbital (HOMO) and lowest unoccupied molecular orbital (LUMO) levels of the coordination polymers were estimated using UV-Vis-NIR and photoelectron spectroscopies, and it was revealed that these coordination polymers have appropriate HOMO levels for use as dye sensitizers. Direct-current electrical conductivity measurements and impedance measurements indicated that these 1D Cu(I)–Ni(II) heterometal coordination polymers were insulators ( σ 300K < 10 ？12 S cm ？1). In addition, the coordination polymers were used as sensitizing materials in dye-sensitized solar cells (DSSCs). DSSCs with 1D Cu(I)–Ni(II) heterometal coordination polymers showed lower performances than those with 1D halide-bridged Cu(I)–Cu(II) mixed-valence coordination polymers.","subitem_description_type":"Abstract"}]},"item_3_description_185":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"Creative Commons Attribution license\n(http://creativecommons.org/licenses/by/3.0/)","subitem_description_type":"Other"}]},"item_3_full_name_183":{"attribute_name":"著者別名","attribute_value_mlt":[{"nameIdentifiers":[{"nameIdentifier":"44878","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"70608471","nameIdentifierScheme":"KAKEN","nameIdentifierURI":"https://nrid.nii.ac.jp/ja/nrid/1000070608471 "}],"names":[{"name":"金, 敬鎬","nameLang":"ja"}]}]},"item_3_publisher_212":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"MDPI"}]},"item_3_relation_191":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"http://doi.org/10.3390/polym4031613","subitem_relation_type_select":"DOI"}}]},"item_3_select_195":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"publisher"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Okubo, Takashi","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Tanaka, Naoya","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Anma, Haruho","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Kim, Kyung Ho","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Maekawa, Masahiko","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Kuroda-Sowa, Takayoshi","creatorNameLang":"en"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2016-11-22"}],"displaytype":"detail","filename":"No252.pdf","filesize":[{"value":"914.3 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"No252.pdf","url":"https://kitami-it.repo.nii.ac.jp/record/7904/files/No252.pdf"},"version_id":"8d5f64aa-19c2-4071-8308-2496d97ab2e0"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"coordination polymer","subitem_subject_scheme":"Other"},{"subitem_subject":"crystal structure","subitem_subject_scheme":"Other"},{"subitem_subject":"electric-conductivity","subitem_subject_scheme":"Other"},{"subitem_subject":"dye-sensitized solar cell","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Dye-sensitized Solar Cells with New One-Dimensional Halide-Bridged Cu(I)-Ni(II) Heterometal Coordination Polymers Containing Hexamethylene Dithiocarbamate Ligand","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Dye-sensitized Solar Cells with New One-Dimensional Halide-Bridged Cu(I)-Ni(II) Heterometal Coordination Polymers Containing Hexamethylene Dithiocarbamate Ligand","subitem_title_language":"en"}]},"item_type_id":"3","owner":"1","path":["87"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2015-08-19"},"publish_date":"2015-08-19","publish_status":"0","recid":"7904","relation_version_is_last":true,"title":["Dye-sensitized Solar Cells with New One-Dimensional Halide-Bridged Cu(I)-Ni(II) Heterometal Coordination Polymers Containing Hexamethylene Dithiocarbamate Ligand"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2022-12-13T02:23:18.424039+00:00"}