{"_buckets": {"deposit": "8960cfeb-0e2c-482c-abcf-071b608df84d"}, "_deposit": {"id": "7610", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "7610"}, "status": "published"}, "_oai": {"id": "oai:kitami-it.repo.nii.ac.jp:00007610"}, "item_3_biblio_info_186": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2010-10", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "16", "bibliographicPageEnd": "2464", "bibliographicPageStart": "2461", "bibliographic_titles": [{"bibliographic_title": "Synlett"}]}]}, "item_3_description_184": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "(Trimethylsilyl)ethynyl bromide can be easily transformed into conjugated (E)-enynones, whose skeleton consists of consecutive carbonyl, ethynyl, and (E)-ethenyl units, via a one-pot multicomponent Suzuki-type reaction-Sonogashira reaction sequence. Thus, a three-component coupling of (trimethylsilyl)ethynyl bromide, (E)-alk-1-enyldisiamylborane and acid chloride is achieved in a two-step, one-pot procedure, in which (E)-alk-1-enyl group is installed as nucleophile in the sp-carbon atom attached to bromine atom and acyl group is installed as electrophile in the other sp-carbon atom.", "subitem_description_type": "Abstract"}, {"subitem_description": "(trimethylsilyl)ethynyl bromide", "subitem_description_type": "Abstract"}]}, "item_3_publisher_212": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "Georg Thieme Verlag Stuttgart"}]}, "item_3_rights_192": {"attribute_name": "\u6a29\u5229", "attribute_value_mlt": [{"subitem_rights": "c Georg Thieme Verlag Stuttgart"}]}, "item_3_select_195": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Hoshi, Masayuki"}], "nameIdentifiers": [{"nameIdentifier": "38972", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Yamazaki, Hirokazu"}], "nameIdentifiers": [{"nameIdentifier": "38973", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Okimoto, Mitsuhiro"}], "nameIdentifiers": [{"nameIdentifier": "38974", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2016-11-22"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "No245.pdf", "filesize": [{"value": "114.9 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 114900.0, "url": {"label": "No245.pdf", "url": "https://kitami-it.repo.nii.ac.jp/record/7610/files/No245.pdf"}, "version_id": "d3893702-b4d0-4240-ac81-7a53e7182c49"}]}, "item_keyword": {"attribute_name": "\u30ad\u30fc\u30ef\u30fc\u30c9", "attribute_value_mlt": [{"subitem_subject": "conjugated enynone", "subitem_subject_scheme": "Other"}, {"subitem_subject": "cross-coupling", "subitem_subject_scheme": "Other"}, {"subitem_subject": "alkenylborane", "subitem_subject_scheme": "Other"}, {"subitem_subject": "acid chloride", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "One-Pot Synthesis of Conjugated (E)-Enynones via Two Types of Cross-Coupling Reaction", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "One-Pot Synthesis of Conjugated (E)-Enynones via Two Types of Cross-Coupling Reaction"}]}, "item_type_id": "3", "owner": "1", "path": ["1"], "permalink_uri": "https://kitami-it.repo.nii.ac.jp/records/7610", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_value": "2014-02-25"}, "publish_date": "2014-02-25", "publish_status": "0", "recid": "7610", "relation": {}, "relation_version_is_last": true, "title": ["One-Pot Synthesis of Conjugated (E)-Enynones via Two Types of Cross-Coupling Reaction"], "weko_shared_id": null}