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One-Pot Synthesis of Conjugated (E)-Enynones via Two Types of Cross-Coupling Reaction
https://kitami-it.repo.nii.ac.jp/records/7610
https://kitami-it.repo.nii.ac.jp/records/7610f616fc64-522c-4951-9a60-6063695f2452
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
No245.pdf (114.9 kB)
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||
|---|---|---|---|---|---|---|
| 公開日 | 2014-02-25 | |||||
| タイトル | ||||||
| タイトル | One-Pot Synthesis of Conjugated (E)-Enynones via Two Types of Cross-Coupling Reaction | |||||
| 言語 | en | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | conjugated enynone | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | cross-coupling | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | alkenylborane | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | acid chloride | |||||
| 資源タイプ | ||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
| 資源タイプ | journal article | |||||
| アクセス権 | ||||||
| アクセス権 | open access | |||||
| アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||
| 著者 |
Hoshi, Masayuki
× Hoshi, Masayuki× Yamazaki, Hirokazu× Okimoto, Mitsuhiro |
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| 抄録 | ||||||
| 内容記述タイプ | Abstract | |||||
| 内容記述 | (Trimethylsilyl)ethynyl bromide can be easily transformed into conjugated (E)-enynones, whose skeleton consists of consecutive carbonyl, ethynyl, and (E)-ethenyl units, via a one-pot multicomponent Suzuki-type reaction-Sonogashira reaction sequence. Thus, a three-component coupling of (trimethylsilyl)ethynyl bromide, (E)-alk-1-enyldisiamylborane and acid chloride is achieved in a two-step, one-pot procedure, in which (E)-alk-1-enyl group is installed as nucleophile in the sp-carbon atom attached to bromine atom and acyl group is installed as electrophile in the other sp-carbon atom. | |||||
| 抄録 | ||||||
| 内容記述タイプ | Abstract | |||||
| 内容記述 | (trimethylsilyl)ethynyl bromide | |||||
| 書誌情報 |
Synlett 号 16, p. 2461-2464, 発行日 2010-10 |
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| 権利 | ||||||
| 権利情報 | c Georg Thieme Verlag Stuttgart | |||||
| 出版者 | ||||||
| 出版者 | Georg Thieme Verlag Stuttgart | |||||
| 著者版フラグ | ||||||
| 値 | author | |||||
| 出版タイプ | ||||||
| 出版タイプ | AM | |||||
| 出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
