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One-Pot Synthesis of Conjugated (E)-Enynones via Two Types of Cross-Coupling Reaction
https://kitami-it.repo.nii.ac.jp/records/7610
https://kitami-it.repo.nii.ac.jp/records/7610f616fc64-522c-4951-9a60-6063695f2452
名前 / ファイル | ライセンス | アクション |
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No245.pdf (114.9 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2014-02-25 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | One-Pot Synthesis of Conjugated (E)-Enynones via Two Types of Cross-Coupling Reaction | |||||
言語 | ||||||
言語 | eng | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | conjugated enynone | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | cross-coupling | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | alkenylborane | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | acid chloride | |||||
資源タイプ | ||||||
資源 | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
アクセス権 | ||||||
アクセス権 | open access | |||||
アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||
著者 |
Hoshi, Masayuki
× Hoshi, Masayuki× Yamazaki, Hirokazu× Okimoto, Mitsuhiro |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | (Trimethylsilyl)ethynyl bromide can be easily transformed into conjugated (E)-enynones, whose skeleton consists of consecutive carbonyl, ethynyl, and (E)-ethenyl units, via a one-pot multicomponent Suzuki-type reaction-Sonogashira reaction sequence. Thus, a three-component coupling of (trimethylsilyl)ethynyl bromide, (E)-alk-1-enyldisiamylborane and acid chloride is achieved in a two-step, one-pot procedure, in which (E)-alk-1-enyl group is installed as nucleophile in the sp-carbon atom attached to bromine atom and acyl group is installed as electrophile in the other sp-carbon atom. | |||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | (trimethylsilyl)ethynyl bromide | |||||
書誌情報 |
Synlett 号 16, p. 2461-2464, 発行日 2010-10 |
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権利 | ||||||
権利情報 | c Georg Thieme Verlag Stuttgart | |||||
出版者 | ||||||
出版者 | Georg Thieme Verlag Stuttgart | |||||
著者版フラグ | ||||||
値 | author | |||||
出版タイプ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa |