{"created":"2021-03-01T06:00:03.782166+00:00","id":7610,"links":{},"metadata":{"_buckets":{"deposit":"8960cfeb-0e2c-482c-abcf-071b608df84d"},"_deposit":{"id":"7610","owners":[],"pid":{"revision_id":0,"type":"depid","value":"7610"},"status":"published"},"_oai":{"id":"oai:kitami-it.repo.nii.ac.jp:00007610","sets":["1:87"]},"author_link":["38972","38973","38974"],"item_1646810750418":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_3_biblio_info_186":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2010-10","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"16","bibliographicPageEnd":"2464","bibliographicPageStart":"2461","bibliographic_titles":[{"bibliographic_title":"Synlett"}]}]},"item_3_description_184":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"(Trimethylsilyl)ethynyl bromide can be easily transformed into conjugated (E)-enynones, whose skeleton consists of consecutive carbonyl, ethynyl, and (E)-ethenyl units, via a one-pot multicomponent Suzuki-type reaction-Sonogashira reaction sequence. Thus, a three-component coupling of (trimethylsilyl)ethynyl bromide, (E)-alk-1-enyldisiamylborane and acid chloride is achieved in a two-step, one-pot procedure, in which (E)-alk-1-enyl group is installed as nucleophile in the sp-carbon atom attached to bromine atom and acyl group is installed as electrophile in the other sp-carbon atom.","subitem_description_type":"Abstract"},{"subitem_description":"(trimethylsilyl)ethynyl bromide","subitem_description_type":"Abstract"}]},"item_3_publisher_212":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Georg Thieme Verlag Stuttgart"}]},"item_3_rights_192":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"c Georg Thieme Verlag Stuttgart"}]},"item_3_select_195":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"author"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Hoshi, Masayuki","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Yamazaki, Hirokazu","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Okimoto, Mitsuhiro","creatorNameLang":"en"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2016-11-22"}],"displaytype":"detail","filename":"No245.pdf","filesize":[{"value":"114.9 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"No245.pdf","url":"https://kitami-it.repo.nii.ac.jp/record/7610/files/No245.pdf"},"version_id":"d3893702-b4d0-4240-ac81-7a53e7182c49"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"conjugated enynone","subitem_subject_scheme":"Other"},{"subitem_subject":"cross-coupling","subitem_subject_scheme":"Other"},{"subitem_subject":"alkenylborane","subitem_subject_scheme":"Other"},{"subitem_subject":"acid chloride","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"One-Pot Synthesis of Conjugated (E)-Enynones via Two Types of Cross-Coupling Reaction","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"One-Pot Synthesis of Conjugated (E)-Enynones via Two Types of Cross-Coupling Reaction","subitem_title_language":"en"}]},"item_type_id":"3","owner":"1","path":["87"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2014-02-25"},"publish_date":"2014-02-25","publish_status":"0","recid":"7610","relation_version_is_last":true,"title":["One-Pot Synthesis of Conjugated (E)-Enynones via Two Types of Cross-Coupling Reaction"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2022-12-13T02:21:02.224306+00:00"}