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The use of 1 M NaOMe as a base exclusively affords both (E)- and (Z)-3-alken-1-ynes with high regio- and stereoselectivity, while the use of LiOH\u30fbH2O instead of 1 M NaOMe preferentially gives both (E)- and (Z)-1-trimethylsilyl-3- alken-1-ynes regio- and stereoselectively.", "subitem_description_type": "Abstract"}]}, "item_3_description_194": {"attribute_name": "\u30d5\u30a9\u30fc\u30de\u30c3\u30c8", "attribute_value_mlt": [{"subitem_description": "application/pdf", "subitem_description_type": "Other"}]}, "item_3_full_name_183": {"attribute_name": "\u8457\u8005\u5225\u540d", "attribute_value_mlt": [{"nameIdentifiers": [{"nameIdentifier": "44871", "nameIdentifierScheme": "WEKO"}, {"nameIdentifier": "1000000113712 ", "nameIdentifierScheme": "NRID", "nameIdentifierURI": "http://rns.nii.ac.jp/d/nr/1000000113712 "}], "names": [{"name": "\u661f, \u96c5\u4e4b"}]}]}, "item_3_publisher_212": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "Georg Thieme Verlag"}]}, "item_3_relation_191": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type_id": {"subitem_relation_type_id_text": "http://doi.org/10.1055/s-2002-32604", "subitem_relation_type_select": "DOI"}}]}, "item_3_rights_192": {"attribute_name": "\u6a29\u5229", "attribute_value_mlt": [{"subitem_rights": "http://www.thieme-connect.de/ejournals/abstract/synthesis/doi/10.1055/s-2002-32604"}, {"subitem_rights": "Georg Thieme Verlag, M.Hoshi, K.Shirakawa, Synlett, 2002(7), 2002, 1101-1104. c 2002 Georg Thieme Verlag KG."}]}, "item_3_select_195": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_3_subject_196": {"attribute_name": "\u65e5\u672c\u5341\u9032\u5206\u985e\u6cd5", "attribute_value_mlt": [{"subitem_subject": "437", "subitem_subject_scheme": "NDC"}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Hoshi, Masayuki"}], "nameIdentifiers": [{"nameIdentifier": "36503", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Shirakawa, Kazuya"}], "nameIdentifiers": [{"nameIdentifier": "36504", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2016-11-22"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "4605.pdf", "filesize": [{"value": "68.2 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 68200.0, "url": {"label": "4605.pdf", "url": "https://kitami-it.repo.nii.ac.jp/record/7175/files/4605.pdf"}, "version_id": "9e61fab7-d57c-43ea-bade-b4771868af6c"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Construction of Terminal Conjugated Enynes: Regio- and Stereoselective Syntheses of 3-Alken-1- ynes and 1-Trimethylsilyl-3-alken-1-ynes from Alkenyldialkylboranes and (Trimethylsilyl)ethynyl Bromide", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Construction of Terminal Conjugated Enynes: Regio- and Stereoselective Syntheses of 3-Alken-1- ynes and 1-Trimethylsilyl-3-alken-1-ynes from Alkenyldialkylboranes and (Trimethylsilyl)ethynyl Bromide"}]}, "item_type_id": "3", "owner": "1", "path": ["1"], "permalink_uri": "https://kitami-it.repo.nii.ac.jp/records/7175", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_value": "2007-05-11"}, "publish_date": "2007-05-11", "publish_status": "0", "recid": "7175", "relation": {}, "relation_version_is_last": true, "title": ["Construction of Terminal Conjugated Enynes: Regio- and Stereoselective Syntheses of 3-Alken-1- ynes and 1-Trimethylsilyl-3-alken-1-ynes from Alkenyldialkylboranes and (Trimethylsilyl)ethynyl Bromide"], "weko_shared_id": 3}