{"created":"2021-03-01T05:59:37.564343+00:00","id":7175,"links":{},"metadata":{"_buckets":{"deposit":"e2b0df1e-968d-4f98-ac56-4d54d271688a"},"_deposit":{"id":"7175","owners":[],"pid":{"revision_id":0,"type":"depid","value":"7175"},"status":"published"},"_oai":{"id":"oai:kitami-it.repo.nii.ac.jp:00007175","sets":["1:87"]},"author_link":["44871","36503","36504"],"item_1646810750418":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_3_biblio_info_186":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2002-07","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"7","bibliographicPageEnd":"1104","bibliographicPageStart":"1101","bibliographicVolumeNumber":"2002","bibliographic_titles":[{"bibliographic_title":"Synlett"}]}]},"item_3_description_184":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The cross-coupling reaction of (E)- and (Z)-1-alkenyldialkylboranes with (trimethylsilyl)ethynyl bromide proceeds in the presence of a base and a catalytic amount of Cu(acac)2 under very mild conditions to provide conjugated enynes whose carbon-carbon triple bond is in distal position. The use of 1 M NaOMe as a base exclusively affords both (E)- and (Z)-3-alken-1-ynes with high regio- and stereoselectivity, while the use of LiOH・H2O instead of 1 M NaOMe preferentially gives both (E)- and (Z)-1-trimethylsilyl-3- alken-1-ynes regio- and stereoselectively.","subitem_description_type":"Abstract"}]},"item_3_description_194":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_3_full_name_183":{"attribute_name":"著者別名","attribute_value_mlt":[{"nameIdentifiers":[{"nameIdentifier":"44871","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"113712","nameIdentifierScheme":"KAKEN","nameIdentifierURI":"https://nrid.nii.ac.jp/ja/nrid/1000000113712 "}],"names":[{"name":"星, 雅之","nameLang":"ja"}]}]},"item_3_publisher_212":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Georg Thieme Verlag"}]},"item_3_relation_191":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"http://doi.org/10.1055/s-2002-32604","subitem_relation_type_select":"DOI"}}]},"item_3_rights_192":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"http://www.thieme-connect.de/ejournals/abstract/synthesis/doi/10.1055/s-2002-32604"},{"subitem_rights":"Georg Thieme Verlag, M.Hoshi, K.Shirakawa, Synlett, 2002(7), 2002, 1101-1104. c 2002 Georg Thieme Verlag KG."}]},"item_3_select_195":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"author"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Hoshi, Masayuki","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Shirakawa, Kazuya","creatorNameLang":"en"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2016-11-22"}],"displaytype":"detail","filename":"4605.pdf","filesize":[{"value":"68.2 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"4605.pdf","url":"https://kitami-it.repo.nii.ac.jp/record/7175/files/4605.pdf"},"version_id":"9e61fab7-d57c-43ea-bade-b4771868af6c"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Construction of Terminal Conjugated Enynes: Regio- and Stereoselective Syntheses of 3-Alken-1- ynes and 1-Trimethylsilyl-3-alken-1-ynes from Alkenyldialkylboranes and (Trimethylsilyl)ethynyl Bromide","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Construction of Terminal Conjugated Enynes: Regio- and Stereoselective Syntheses of 3-Alken-1- ynes and 1-Trimethylsilyl-3-alken-1-ynes from Alkenyldialkylboranes and (Trimethylsilyl)ethynyl Bromide","subitem_title_language":"en"}]},"item_type_id":"3","owner":"1","path":["87"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2007-05-11"},"publish_date":"2007-05-11","publish_status":"0","recid":"7175","relation_version_is_last":true,"title":["Construction of Terminal Conjugated Enynes: Regio- and Stereoselective Syntheses of 3-Alken-1- ynes and 1-Trimethylsilyl-3-alken-1-ynes from Alkenyldialkylboranes and (Trimethylsilyl)ethynyl Bromide"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2022-12-13T02:20:34.767824+00:00"}