WEKO3
アイテム
Fine Structure of the Temperature Programmed Reaction Spectra of Silver Acetate Visualized by a Mass Spectrometer
https://kitami-it.repo.nii.ac.jp/records/6589
https://kitami-it.repo.nii.ac.jp/records/65892d996e43-56d3-4d19-9a78-a84e9e7a2799
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
17-2-8.pdf (4.6 MB)
|
|
| Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||
|---|---|---|---|---|---|---|
| 公開日 | 2007-04-09 | |||||
| タイトル | ||||||
| タイトル | Fine Structure of the Temperature Programmed Reaction Spectra of Silver Acetate Visualized by a Mass Spectrometer | |||||
| 言語 | en | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| 資源タイプ | ||||||
| 資源 | http://purl.org/coar/resource_type/c_6501 | |||||
| タイプ | departmental bulletin paper | |||||
| 著者 |
Masahito, UJIIE
× Masahito, UJIIE× Tohru, KANNO× Masayoshi, KOBAYASHI |
|||||
| 抄録 | ||||||
| 内容記述タイプ | Abstract | |||||
| 内容記述 | The Temperature Programmed Reaction (TPR) spectra of solid silver acetate were finely visualized by using a mass spectrometer assisted by a personal computer. The TPR spectra obtained exhibited only two products, CO_2 and CH_3COOH. The population and the TPR spectra-pattern of the two products were sensitively affected by the rate of temperature rise and the gas atmosphere, in O_2, He or H_2, indicating the different reaction mechanisms depending on were commonly produced in O_2 or He. For the formation of CO_2 four different reaction intermediates were presumed, whereas for the formation of CH_3COOH in O_2, He and H_2, two reaction pathes would be presumed to supply active hydrogen for the hydrogenation of silver acetate. The activation energy to form CO_2 was evaluated to be 32±4 kcal/mol in He, which shifted extremely depending on the gas atmosphere. | |||||
| 言語 | en | |||||
| 書誌情報 |
ja : 北見工業大学研究報告 巻 17, 号 2, p. 191-201, 発行日 1986-03 |
|||||
| フォーマット | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | application/pdf | |||||
| 著者版フラグ | ||||||
| 言語 | en | |||||
| 値 | publisher | |||||
| 出版者 | ||||||
| 出版者 | 北見工業大学 | |||||
| 言語 | ja | |||||
