{"_buckets": {"deposit": "3eaaa89c-0f92-4167-b404-f3175030d33d"}, "_deposit": {"id": "6589", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "6589"}, "status": "published"}, "_oai": {"id": "oai:kitami-it.repo.nii.ac.jp:00006589"}, "item_2_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "1986-03", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "2", "bibliographicPageEnd": "201", "bibliographicPageStart": "191", "bibliographicVolumeNumber": "17", "bibliographic_titles": [{"bibliographic_title": "\u5317\u898b\u5de5\u696d\u5927\u5b66\u7814\u7a76\u5831\u544a"}]}]}, "item_2_description_14": {"attribute_name": "\u30d5\u30a9\u30fc\u30de\u30c3\u30c8", "attribute_value_mlt": [{"subitem_description": "application/pdf", "subitem_description_type": "Other"}]}, "item_2_description_4": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "The Temperature Programmed Reaction (TPR) spectra of solid silver acetate were finely visualized by using a mass spectrometer assisted by a personal computer. The TPR spectra obtained exhibited only two products, CO_2 and CH_3COOH. The population and the TPR spectra-pattern of the two products were sensitively affected by the rate of temperature rise and the gas atmosphere, in O_2, He or H_2, indicating the different reaction mechanisms depending on were commonly produced in O_2 or He. For the formation of CO_2 four different reaction intermediates were presumed, whereas for the formation of CH_3COOH in O_2, He and H_2, two reaction pathes would be presumed to supply active hydrogen for the hydrogenation of silver acetate. The activation energy to form CO_2 was evaluated to be 32\u00b14 kcal/mol in He, which shifted extremely depending on the gas atmosphere.", "subitem_description_type": "Abstract"}]}, "item_2_publisher_32": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "\u5317\u898b\u5de5\u696d\u5927\u5b66"}]}, "item_2_select_15": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "publisher"}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Masahito, UJIIE"}], "nameIdentifiers": [{"nameIdentifier": "33193", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Tohru, KANNO"}], "nameIdentifiers": [{"nameIdentifier": "33194", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Masayoshi, KOBAYASHI"}], "nameIdentifiers": [{"nameIdentifier": "33195", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2016-11-22"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "17-2-8.pdf", "filesize": [{"value": "4.6 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 4600000.0, "url": {"label": "17-2-8.pdf", "url": "https://kitami-it.repo.nii.ac.jp/record/6589/files/17-2-8.pdf"}, "version_id": "30645afd-2bc0-4df2-89a4-d6ef88032bff"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "departmental bulletin paper", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Fine Structure of the Temperature Programmed Reaction Spectra of Silver Acetate Visualized by a Mass Spectrometer", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Fine Structure of the Temperature Programmed Reaction Spectra of Silver Acetate Visualized by a Mass Spectrometer"}]}, "item_type_id": "2", "owner": "1", "path": ["7/15/38"], "permalink_uri": "https://kitami-it.repo.nii.ac.jp/records/6589", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_value": "2007-04-09"}, "publish_date": "2007-04-09", "publish_status": "0", "recid": "6589", "relation": {}, "relation_version_is_last": true, "title": ["Fine Structure of the Temperature Programmed Reaction Spectra of Silver Acetate Visualized by a Mass Spectrometer"], "weko_shared_id": 3}