{"created":"2021-03-01T05:59:01.539728+00:00","id":6589,"links":{},"metadata":{"_buckets":{"deposit":"3eaaa89c-0f92-4167-b404-f3175030d33d"},"_deposit":{"id":"6589","owners":[],"pid":{"revision_id":0,"type":"depid","value":"6589"},"status":"published"},"_oai":{"id":"oai:kitami-it.repo.nii.ac.jp:00006589","sets":["7:15:38"]},"item_2_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1986-03","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"2","bibliographicPageEnd":"201","bibliographicPageStart":"191","bibliographicVolumeNumber":"17","bibliographic_titles":[{"bibliographic_title":"北見工業大学研究報告"}]}]},"item_2_description_14":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_2_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The Temperature Programmed Reaction (TPR) spectra of solid silver acetate were finely visualized by using a mass spectrometer assisted by a personal computer. The TPR spectra obtained exhibited only two products, CO_2 and CH_3COOH. The population and the TPR spectra-pattern of the two products were sensitively affected by the rate of temperature rise and the gas atmosphere, in O_2, He or H_2, indicating the different reaction mechanisms depending on were commonly produced in O_2 or He. For the formation of CO_2 four different reaction intermediates were presumed, whereas for the formation of CH_3COOH in O_2, He and H_2, two reaction pathes would be presumed to supply active hydrogen for the hydrogenation of silver acetate. The activation energy to form CO_2 was evaluated to be 32±4 kcal/mol in He, which shifted extremely depending on the gas atmosphere.","subitem_description_type":"Abstract"}]},"item_2_publisher_32":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"北見工業大学"}]},"item_2_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"publisher"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Masahito, UJIIE"}],"nameIdentifiers":[{"nameIdentifier":"33193","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Tohru, KANNO"}],"nameIdentifiers":[{"nameIdentifier":"33194","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Masayoshi, KOBAYASHI"}],"nameIdentifiers":[{"nameIdentifier":"33195","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2016-11-22"}],"displaytype":"detail","filename":"17-2-8.pdf","filesize":[{"value":"4.6 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"17-2-8.pdf","url":"https://kitami-it.repo.nii.ac.jp/record/6589/files/17-2-8.pdf"},"version_id":"30645afd-2bc0-4df2-89a4-d6ef88032bff"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Fine Structure of the Temperature Programmed Reaction Spectra of Silver Acetate Visualized by a Mass Spectrometer","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Fine Structure of the Temperature Programmed Reaction Spectra of Silver Acetate Visualized by a Mass Spectrometer"}]},"item_type_id":"2","owner":"1","path":["38"],"pubdate":{"attribute_name":"公開日","attribute_value":"2007-04-09"},"publish_date":"2007-04-09","publish_status":"0","recid":"6589","relation_version_is_last":true,"title":["Fine Structure of the Temperature Programmed Reaction Spectra of Silver Acetate Visualized by a Mass Spectrometer"],"weko_creator_id":"1","weko_shared_id":3},"updated":"2022-12-13T02:19:55.131228+00:00"}