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Transient Kinetics in the oxidation of Carbon Monoxide over a Silver Catalyst
https://kitami-it.repo.nii.ac.jp/records/6556
https://kitami-it.repo.nii.ac.jp/records/65566abe3273-ddb6-4327-99f0-fcca2ff9dd19
名前 / ファイル | ライセンス | アクション |
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Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||
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公開日 | 2007-04-09 | |||||
タイトル | ||||||
タイトル | Transient Kinetics in the oxidation of Carbon Monoxide over a Silver Catalyst | |||||
言語 | en | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源 | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | departmental bulletin paper | |||||
著者 |
Masayoshi, KOBAYASHI
× Masayoshi, KOBAYASHI× Hiroshi, TAKEGAMI× Toshikazu, MORI× Nobuo, TAKAHASHI |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | The oxidation of carbon monoxide by nitrous oxide and oxygen over a silver catalyst at 20 C is analysed by both the Hougen-Watson procedure and the transient response method. The rival models derived from the Hougen-Watson procedure are not available to explain the transient response curves of N_2 and CO_2 caused by the concentration jump of CO and N_2O. A sound mechanism derived from the view based on the experimental transient behavior is visualized, and the kinetic parameters in all elementary steps in the reaction sequence are calculated as several parameter sets. From those rival parameter sets the best one is separately determined for the two CO oxdiations with N_2O and O_2, even though the two reactions contain some overlapped elementary steps, supporting the experimental finding on the heterogeneity of silver surface. The best parameter set obtained for the respective reaction consistently explained an transient behavior. | |||||
言語 | en | |||||
書誌情報 |
ja : 北見工業大学研究報告 巻 15, 号 1, p. 87-101, 発行日 1983-11 |
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フォーマット | ||||||
内容記述タイプ | Other | |||||
内容記述 | application/pdf | |||||
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言語 | en | |||||
値 | publisher | |||||
出版者 | ||||||
出版者 | 北見工業大学 | |||||
言語 | ja |