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  1. 紀要掲載論文
  2. 北見工業大学研究報告
  3. Vol.15

Transient Kinetics in the oxidation of Carbon Monoxide over a Silver Catalyst

https://kitami-it.repo.nii.ac.jp/records/6556
6abe3273-ddb6-4327-99f0-fcca2ff9dd19
名前 / ファイル ライセンス アクション
15-1-8.pdf 15-1-8.pdf (6.0 MB)
Item type 紀要論文 / Departmental Bulletin Paper(1)
公開日 2007-04-09
タイトル
タイトル Transient Kinetics in the oxidation of Carbon Monoxide over a Silver Catalyst
言語
言語 eng
資源タイプ
資源 http://purl.org/coar/resource_type/c_6501
タイプ departmental bulletin paper
著者 Masayoshi, KOBAYASHI

× Masayoshi, KOBAYASHI

WEKO 33063

Masayoshi, KOBAYASHI

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Hiroshi, TAKEGAMI

× Hiroshi, TAKEGAMI

WEKO 33064

Hiroshi, TAKEGAMI

Search repository
Toshikazu, MORI

× Toshikazu, MORI

WEKO 33065

Toshikazu, MORI

Search repository
Nobuo, TAKAHASHI

× Nobuo, TAKAHASHI

WEKO 33066

Nobuo, TAKAHASHI

Search repository
抄録
内容記述タイプ Abstract
内容記述 The oxidation of carbon monoxide by nitrous oxide and oxygen over a silver catalyst at 20 C is analysed by both the Hougen-Watson procedure and the transient response method. The rival models derived from the Hougen-Watson procedure are not available to explain the transient response curves of N_2 and CO_2 caused by the concentration jump of CO and N_2O. A sound mechanism derived from the view based on the experimental transient behavior is visualized, and the kinetic parameters in all elementary steps in the reaction sequence are calculated as several parameter sets. From those rival parameter sets the best one is separately determined for the two CO oxdiations with N_2O and O_2, even though the two reactions contain some overlapped elementary steps, supporting the experimental finding on the heterogeneity of silver surface. The best parameter set obtained for the respective reaction consistently explained an transient behavior.
書誌情報 北見工業大学研究報告

巻 15, 号 1, p. 87-101, 発行日 1983-11
フォーマット
内容記述タイプ Other
内容記述 application/pdf
著者版フラグ
値 publisher
出版者
出版者 北見工業大学
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