@article{oai:kitami-it.repo.nii.ac.jp:00006556, author = {Masayoshi, KOBAYASHI and Hiroshi, TAKEGAMI and Toshikazu, MORI and Nobuo, TAKAHASHI}, issue = {1}, journal = {北見工業大学研究報告}, month = {Nov}, note = {application/pdf, The oxidation of carbon monoxide by nitrous oxide and oxygen over a silver catalyst at 20 C is analysed by both the Hougen-Watson procedure and the transient response method. The rival models derived from the Hougen-Watson procedure are not available to explain the transient response curves of N_2 and CO_2 caused by the concentration jump of CO and N_2O. A sound mechanism derived from the view based on the experimental transient behavior is visualized, and the kinetic parameters in all elementary steps in the reaction sequence are calculated as several parameter sets. From those rival parameter sets the best one is separately determined for the two CO oxdiations with N_2O and O_2, even though the two reactions contain some overlapped elementary steps, supporting the experimental finding on the heterogeneity of silver surface. The best parameter set obtained for the respective reaction consistently explained an transient behavior.}, pages = {87--101}, title = {Transient Kinetics in the oxidation of Carbon Monoxide over a Silver Catalyst}, volume = {15}, year = {1983} }