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  1. 紀要掲載論文
  2. 北見工業大学研究報告
  3. Vol.8

沈殿法によるリン酸アルミニウム触媒の調製とその n-ブタノール脱水反応活性

https://kitami-it.repo.nii.ac.jp/records/6424
5ffece4e-6da8-4041-bae2-bcaf5da85875
名前 / ファイル ライセンス アクション
8-2-7.pdf 8-2-7.pdf (4.1 MB)
Item type 紀要論文 / Departmental Bulletin Paper(1)
公開日 2007-04-09
タイトル
タイトル 沈殿法によるリン酸アルミニウム触媒の調製とその n-ブタノール脱水反応活性
言語
言語 jpn
資源タイプ
資源 http://purl.org/coar/resource_type/c_6501
タイプ departmental bulletin paper
その他のタイトル
その他のタイトル Preparation of Aluminum Phosphate by Precipitation Method and its Catalytic Activity in n-Butanol Dehydration
著者 伊藤, 英信

× 伊藤, 英信

WEKO 32531

伊藤, 英信

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吉田, 正敏

× 吉田, 正敏

WEKO 32532

吉田, 正敏

Search repository
多田, 旭男

× 多田, 旭男

WEKO 32533

多田, 旭男

Search repository
著者別名
識別子
識別子 32534
識別子Scheme WEKO
姓名
姓名 ITOH, Hidenobu
著者別名
識別子
識別子 32535
識別子Scheme WEKO
姓名
姓名 YOSHIDA, Masatoshi
著者別名
識別子
識別子 32536
識別子Scheme WEKO
姓名
姓名 TADA, Akio
抄録
内容記述タイプ Abstract
内容記述 The circumstances in the preparation of aluminum phosphate catalyst which control the properties of the catalyst have been investigated for the phosphate prepared from a solution of aluminum salt and phosphoric acid by addition of ammonia. Surface area, acidity, and catalytic activity have been used to characterize the catalyst. The rate of addition of ammonia, final pH, washing of precipitate, temperature of heat-treatment, and kind of aluminum salt were found to affect the nature of the resulting catalyst. Aluminum phosphates obtained from nitrate and chloride(N- and C-AIphosphate) had higher total acid amounts and larger surface areas than aluminum phosphate obtained from sulfate(S-AI-phosphate), but the latter showed higher catalytic activity than the former. The former catalyzed the dehydration of n-butanol to form ether rather than olefin, while the latter catalyzed selectively to form olefin. For the Former, the 1-butene content and the ratio of cis- to trans-2-butene were higher than the equilibrium values; whereas for the latter, there was a clear trend toward a decrease in 1-butene and an increase in the 2-butene isomers as the conversion increased. The effects of final pH and washing were remarkable for S-AI-phosphate.
書誌情報 北見工業大学研究報告

巻 8, 号 2, p. 203-212, 発行日 1977-03
フォーマット
内容記述タイプ Other
内容記述 application/pdf
著者版フラグ
値 publisher
出版者
出版者 北見工業大学
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