| Item type |
学術雑誌論文 / Journal Article(1) |
| 公開日 |
2015-09-09 |
| タイトル |
|
|
タイトル |
Preparation of optically pure δ-lactones using diastereomeric resolution with amino acid as resolving agent |
|
言語 |
en |
| 言語 |
|
|
言語 |
eng |
| キーワード |
|
|
主題Scheme |
Other |
|
主題 |
δ-lactone |
| キーワード |
|
|
主題Scheme |
Other |
|
主題 |
diastereomeric resolution |
| キーワード |
|
|
主題Scheme |
Other |
|
主題 |
resolving agent |
| キーワード |
|
|
主題Scheme |
Other |
|
主題 |
amino acid |
| 資源タイプ |
|
|
資源 |
http://purl.org/coar/resource_type/c_6501 |
|
タイプ |
journal article |
| アクセス権 |
|
|
アクセス権 |
open access |
|
アクセス権URI |
http://purl.org/coar/access_right/c_abf2 |
| 著者 |
Shimotori, Yasutaka
Hoshi, Masayuki
Seki, Syota
Osanai, Takeshi
Okabe, Hayato
Ikeda, Yoshitaka
Miyakoshi, Tetsuo
|
| 抄録 |
|
|
内容記述タイプ |
Abstract |
|
内容記述 |
Synthesis of optically pure δ-lactones by diastereomeric resolution was investigated. Amino acid derivatives, which can be obtained at a relatively low cost, were used as resolving agents. Six optically pure δ-lactones were efficiently synthesized using Cbz-L-alanine without other expensive resolving agents. Both enantiomers of δ-lactone obtained had over 98% enantiomeric excesses. This diastereomeric resolution is very efficient for the preparation of optically pure δ-lactones. |
| 書誌情報 |
Journal of Oleo Science
巻 64,
号 1,
p. 75-90,
発行日 2015
|
| DOI |
|
|
|
識別子タイプ |
DOI |
|
|
関連識別子 |
http://doi.org/10.5650/jos.ess14124 |
| 権利 |
|
|
権利情報 |
c 2015 by Japan Oil Chemists' Society |
| 出版者 |
|
|
出版者 |
Japan Oil Chemists' Society (公益社団法人日本油化学会) |
|
言語 |
en |
| 著者版フラグ |
|
|
言語 |
en |
|
値 |
publisher |
| 出版タイプ |
|
|
出版タイプ |
VoR |
|
出版タイプResource |
http://purl.org/coar/version/c_970fb48d4fbd8a85 |
2015_Preparation of optically pure δ-lactones using diastereomeric resolution with amino acid as resolving agent.pdf (633.8 kB)
