| Item type |
学術雑誌論文 / Journal Article(1) |
| 公開日 |
2009-03-30 |
| タイトル |
|
|
タイトル |
Electrooxidative Cyclization of Benzylidenaminothiophenols to the Corresponding 2-Arylbenzothiazoles |
|
言語 |
en |
| 言語 |
|
|
言語 |
eng |
| 資源タイプ |
|
|
資源 |
http://purl.org/coar/resource_type/c_6501 |
|
タイプ |
journal article |
| アクセス権 |
|
|
アクセス権 |
open access |
|
アクセス権URI |
http://purl.org/coar/access_right/c_abf2 |
| 著者 |
Okimoto, Mitsuhiro
Yoshida, Takashi
Hoshi, Masayuki
Hattori, Kazuyuki
Komata, Masashi
Tomozawa, Kenta
Chiba, Tomohito
|
| 抄録 |
|
|
内容記述タイプ |
Abstract |
|
内容記述 |
Several benzylideneaminothiophenols were electrochemically oxidized in methanol containing sodium acetate as the supporting electrolyte, to afford the corresponding 2-arylbenzothiazols. The reaction proceeded via intramolecular cyclization involving the formation of a new bond between the benzylic carbon of the substrate and the sulfur of the thiol group. Based on the yields, room temperature and the use of two equivalents of sodium acetate relative to the substrate as the supporting electrolyte were found to be the optimal reaction conditions. The electrooxidation presumably involves a two-electron oxidation process. |
| 内容記述 |
|
|
内容記述タイプ |
Other |
|
内容記述 |
Copyright c 2009 The Japan Institute of Heterocyclic Chemistry
http://www.heterocycles.jp/library/abstract.php?article=2797 |
| 書誌情報 |
Heterocycles
巻 75,
号 1,
p. 35-42,
発行日 2008-01
|
| DOI |
|
|
|
識別子タイプ |
DOI |
|
|
関連識別子 |
http://doi.org/10.3987/COM-07-11195 |
| フォーマット |
|
|
内容記述タイプ |
Other |
|
内容記述 |
application/pdf |
| 出版者 |
|
|
出版者 |
The Japan Institute of Heterocyclic Chemistry |
|
言語 |
en |
| 著者版フラグ |
|
|
言語 |
en |
|
値 |
author |
| 出版タイプ |
|
|
出版タイプ |
AM |
|
出版タイプResource |
http://purl.org/coar/version/c_ab4af688f83e57aa |
169 Heterocycles(KIT).pdf (119 KB)
