{"_buckets": {"deposit": "76460eb9-a0b8-429d-8d11-3e5d06e6f358"}, "_deposit": {"id": "7235", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "7235"}, "status": "published"}, "_oai": {"id": "oai:kitami-it.repo.nii.ac.jp:00007235"}, "item_3_biblio_info_186": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2007-01-01", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "1", "bibliographicPageEnd": "124", "bibliographicPageStart": "119", "bibliographicVolumeNumber": "41", "bibliographic_titles": [{"bibliographic_title": "Tetrahedron Letters"}]}]}, "item_3_description_184": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "A convenient, efficient and stereoselective synthesis of a range of bis(alk-3-en-1-ynyl)benzenes with E- and Z-configuration is described. The protocol involves Cu-mediated cross-coupling reaction of (E)- and (Z)-alk-1-enyldisiamylboranes with (trimethylsilyl)ethynyl bromide and Pd/Cu-catalyzed cross-coupling reaction with diiodobenzene. The sequential cross-coupling reaction proceeds readily under extremely mild conditions in a one-pot manner to afford bis(alk-3-en-1-ynyl)benzenes in good to excellent yields. The optical properties of the products are also described.", "subitem_description_type": "Abstract"}]}, "item_3_description_185": {"attribute_name": "\u5185\u5bb9\u8a18\u8ff0", "attribute_value_mlt": [{"subitem_description": "NOTICE: This is the author\u0027s version of a work accepted for publication by Elsevier. Changes resulting from the publishing process, including peer review, editing, corrections, structual formatting and other quality control mechanisms , may not be reflected in this document. Changes may have been to this work since it was submitted for publication.", "subitem_description_type": "Other"}]}, "item_3_description_194": {"attribute_name": "\u30d5\u30a9\u30fc\u30de\u30c3\u30c8", "attribute_value_mlt": [{"subitem_description": "application/pdf", "subitem_description_type": "Other"}]}, "item_3_publisher_212": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "Elsevier"}]}, "item_3_relation_191": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type_id": {"subitem_relation_type_id_text": "http://dx.doi.org/10.1016/j.tetlet.2006.10.162", "subitem_relation_type_select": "DOI"}}]}, "item_3_select_195": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Hoshi, Masayuki"}], "nameIdentifiers": [{"nameIdentifier": "37095", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Suzuki, Souichi"}], "nameIdentifiers": [{"nameIdentifier": "37096", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Saitoh, Shingo"}], "nameIdentifiers": [{"nameIdentifier": "37097", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Okimoto, Mitsuhiro"}], "nameIdentifiers": [{"nameIdentifier": "37098", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Shirakawa, Kazuya"}], "nameIdentifiers": [{"nameIdentifier": "37099", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2016-11-22"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "tl-0609-447.pdf", "filesize": [{"value": "310.5 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 310500.0, "url": {"label": "tl-0609-447.pdf", "url": "https://kitami-it.repo.nii.ac.jp/record/7235/files/tl-0609-447.pdf"}, "version_id": "a1417328-193f-448f-bed7-7abb6d92c5fe"}]}, "item_keyword": {"attribute_name": "\u30ad\u30fc\u30ef\u30fc\u30c9", "attribute_value_mlt": [{"subitem_subject": "Bis(alk-3-en-1-ynyl)benzene", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Cross-coupling", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Alkenylborane", "subitem_subject_scheme": "Other"}, {"subitem_subject": "(Trimethylsilyl)ethynyl bromide", "subitem_subject_scheme": "Other"}, {"subitem_subject": "Diiodobenzene", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Synthesis of bis(alk-3-en-1-ynyl)benzene with either E- or Z-configuration via a one-pot three-component coupling reaction and its optical properties", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Synthesis of bis(alk-3-en-1-ynyl)benzene with either E- or Z-configuration via a one-pot three-component coupling reaction and its optical properties"}]}, "item_type_id": "3", "owner": "1", "path": ["1"], "permalink_uri": "https://kitami-it.repo.nii.ac.jp/records/7235", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_value": "2008-01-25"}, "publish_date": "2008-01-25", "publish_status": "0", "recid": "7235", "relation": {}, "relation_version_is_last": true, "title": ["Synthesis of bis(alk-3-en-1-ynyl)benzene with either E- or Z-configuration via a one-pot three-component coupling reaction and its optical properties"], "weko_shared_id": null}