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  1. 学術雑誌掲載済論文
  2. 洋雑誌

Synthesis of bis(alk-3-en-1-ynyl)benzene with either E- or Z-configuration via a one-pot three-component coupling reaction and its optical properties

https://kitami-it.repo.nii.ac.jp/records/7235
8be4ce92-5a39-4d64-b672-08df365133df
名前 / ファイル ライセンス アクション
tl-0609-447.pdf tl-0609-447.pdf (310.5 kB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2008-01-25
タイトル
言語 en
タイトル Synthesis of bis(alk-3-en-1-ynyl)benzene with either E- or Z-configuration via a one-pot three-component coupling reaction and its optical properties
言語
言語 eng
キーワード
主題Scheme Other
主題 Bis(alk-3-en-1-ynyl)benzene
キーワード
主題Scheme Other
主題 Cross-coupling
キーワード
主題Scheme Other
主題 Alkenylborane
キーワード
主題Scheme Other
主題 (Trimethylsilyl)ethynyl bromide
キーワード
主題Scheme Other
主題 Diiodobenzene
資源タイプ
資源 http://purl.org/coar/resource_type/c_6501
タイプ journal article
アクセス権
アクセス権 open access
アクセス権URI http://purl.org/coar/access_right/c_abf2
著者 Hoshi, Masayuki

× Hoshi, Masayuki

WEKO 37095

en Hoshi, Masayuki

Search repository
Suzuki, Souichi

× Suzuki, Souichi

WEKO 37096

en Suzuki, Souichi

Search repository
Saitoh, Shingo

× Saitoh, Shingo

WEKO 37097

en Saitoh, Shingo

Search repository
Okimoto, Mitsuhiro

× Okimoto, Mitsuhiro

WEKO 37098

en Okimoto, Mitsuhiro

Search repository
Shirakawa, Kazuya

× Shirakawa, Kazuya

WEKO 37099

en Shirakawa, Kazuya

Search repository
抄録
内容記述タイプ Abstract
内容記述 A convenient, efficient and stereoselective synthesis of a range of bis(alk-3-en-1-ynyl)benzenes with E- and Z-configuration is described. The protocol involves Cu-mediated cross-coupling reaction of (E)- and (Z)-alk-1-enyldisiamylboranes with (trimethylsilyl)ethynyl bromide and Pd/Cu-catalyzed cross-coupling reaction with diiodobenzene. The sequential cross-coupling reaction proceeds readily under extremely mild conditions in a one-pot manner to afford bis(alk-3-en-1-ynyl)benzenes in good to excellent yields. The optical properties of the products are also described.
内容記述
内容記述タイプ Other
内容記述 NOTICE: This is the author's version of a work accepted for publication by Elsevier. Changes resulting from the publishing process, including peer review, editing, corrections, structual formatting and other quality control mechanisms , may not be reflected in this document. Changes may have been to this work since it was submitted for publication.
書誌情報 Tetrahedron Letters

巻 41, 号 1, p. 119-124, 発行日 2007-01-01
DOI
関連識別子
識別子タイプ DOI
関連識別子 https://doi.org/10.1016/j.tetlet.2006.10.162
フォーマット
内容記述タイプ Other
内容記述 application/pdf
出版者
出版者 Elsevier
著者版フラグ
値 author
出版タイプ
出版タイプ AM
出版タイプResource http://purl.org/coar/version/c_ab4af688f83e57aa
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