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Selective Ultratrace Detection of Al(III) and Ga(III) Complexed with a Calcein Isomer by Capillary Zone Electrophoresis with Laser-induced Fluorescent Detection: Comparison of Emissive Polyaminocarboxylates as Derivatizing Ligands
https://kitami-it.repo.nii.ac.jp/records/6896
https://kitami-it.repo.nii.ac.jp/records/6896d8aa801d-470b-441f-b843-e2e7d08cf65a
名前 / ファイル | ライセンス | アクション |
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5067.pdf (204.5 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2007-04-19 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Selective Ultratrace Detection of Al(III) and Ga(III) Complexed with a Calcein Isomer by Capillary Zone Electrophoresis with Laser-induced Fluorescent Detection: Comparison of Emissive Polyaminocarboxylates as Derivatizing Ligands | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源 | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
アクセス権 | ||||||
アクセス権 | open access | |||||
アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||
著者 |
Saito, Shingo
× Saito, Shingo× Shimidzu, Jun-ichi× Yoshimoto, Keitaro× Maeda, Mizuo× Aoyama, Masakazu |
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著者別名 | ||||||
姓名 | 青山, 政和 | |||||
言語 | ja | |||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | A highly sensitive and selective capillary zone electrophoresis with laser-induced fluorescent detection (CZE-LIF) for Al^<3+> and Ga^<3+> was developed using a calcein 4’,5’-isomer as a pre-capillary complexing agent. Direct fluorescent detection without an agent added to the carrier buffer provided the notable detection limits of 3.9 × 10^<-10> and 4.6 × 10^<-10> mol dm^<-3> for Al and Ga, respectively. By applying a river water sample successfully to this system, its potential for practical applications was ascertained. A comparison of three aromatic polyaminocarboxylate ligands related to the coordination structure and the distance between the fluorophore and the chelating moiety, revealed some interesting factors regarding their selectivity | |||||
書誌情報 |
Journal of Chromatography A 巻 1140, 号 1-2, p. 230-235, 発行日 2007-01 |
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DOI | ||||||
識別子タイプ | DOI | |||||
関連識別子 | http://doi.org/10.1016/j.chroma.2006.12.001 | |||||
権利 | ||||||
権利情報 | http://www.sciencedirect.com/science/journal/00219673 | |||||
権利 | ||||||
権利情報 | Elsevier B.V., Shingo Saito, Jun-ichi Shimidzu, Keitaro Yoshimoto, Mizuo Maeda and Masakazu Aoyama, Journal of Chromatography A, 1140(1-2), 2007, 230-235. | |||||
フォーマット | ||||||
内容記述タイプ | Other | |||||
内容記述 | application/pdf | |||||
出版者 | ||||||
出版者 | Elsevier | |||||
著者版フラグ | ||||||
値 | author | |||||
出版タイプ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa |