{"_buckets": {"deposit": "ed207c98-b517-4ff2-92dd-5d64d30029eb"}, "_deposit": {"id": "6649", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "6649"}, "status": "published"}, "_oai": {"id": "oai:kitami-it.repo.nii.ac.jp:00006649"}, "item_2_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "1989-11", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "1", "bibliographicPageEnd": "95", "bibliographicPageStart": "81", "bibliographicVolumeNumber": "21", "bibliographic_titles": [{"bibliographic_title": "\u5317\u898b\u5de5\u696d\u5927\u5b66\u7814\u7a76\u5831\u544a"}]}]}, "item_2_description_14": {"attribute_name": "\u30d5\u30a9\u30fc\u30de\u30c3\u30c8", "attribute_value_mlt": [{"subitem_description": "application/pdf", "subitem_description_type": "Other"}]}, "item_2_description_4": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "The kinetics of the hydration of propene on a Solid Polymer Electrolyte (SPE) and a silver-supported one have been studied by using the steady state and unsteady state methods at a temperature range of 100?160\u2103, using an ordinary now reactor under atmospheric pressure. The reaction gave two products in parallel reaction, iso-propylalcohol and hexane, and the reaction rates are represented as follows \u03b3_\u003cP\u03b3OH\u003e=\u03baPc_3H_6PH_2O^m and\u03b3_\u003chex\u003e=\u03baPc_3H_6PH_2O^n with activation energies 46 and 90 kJ/mol, respectively. All the transient response curves caused by the concentration jump of propene gave a monotonic mode suggesting a Langmuir-Hinshelwood mechanism with the rate controlling step of carbenium ion formation.", "subitem_description_type": "Abstract"}]}, "item_2_publisher_32": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "\u5317\u898b\u5de5\u696d\u5927\u5b66"}]}, "item_2_select_15": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "publisher"}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Tohru, KANNO"}], "nameIdentifiers": [{"nameIdentifier": "33580", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Yukitoshi, TATSUMOTO"}], "nameIdentifiers": [{"nameIdentifier": "33581", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Masayoshi, KOBAYASHI"}], "nameIdentifiers": [{"nameIdentifier": "33582", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2016-11-22"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "21-1-6.pdf", "filesize": [{"value": "5.5 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 5500000.0, "url": {"label": "21-1-6.pdf", "url": "https://kitami-it.repo.nii.ac.jp/record/6649/files/21-1-6.pdf"}, "version_id": "a30bd7d6-2dcb-4b9e-b589-00a4f7a861da"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "departmental bulletin paper", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Kinetics of Gas-Phase Hydration of Propene Heterogeneously Catalysed on a Solid Polymer Electrolyte*", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Kinetics of Gas-Phase Hydration of Propene Heterogeneously Catalysed on a Solid Polymer Electrolyte*"}]}, "item_type_id": "2", "owner": "1", "path": ["7/15/42"], "permalink_uri": "https://kitami-it.repo.nii.ac.jp/records/6649", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_value": "2007-04-09"}, "publish_date": "2007-04-09", "publish_status": "0", "recid": "6649", "relation": {}, "relation_version_is_last": true, "title": ["Kinetics of Gas-Phase Hydration of Propene Heterogeneously Catalysed on a Solid Polymer Electrolyte*"], "weko_shared_id": 3}