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Kinetics of Gas-Phase Hydration of Propene Heterogeneously Catalysed on a Solid Polymer Electrolyte
https://kitami-it.repo.nii.ac.jp/records/6649
https://kitami-it.repo.nii.ac.jp/records/66494d3bbf8f-360a-4fdc-b61b-b5e0bf4e5f22
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
21-1-6.pdf (5.5 MB)
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| Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||
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| 公開日 | 2007-04-09 | |||||
| タイトル | ||||||
| タイトル | Kinetics of Gas-Phase Hydration of Propene Heterogeneously Catalysed on a Solid Polymer Electrolyte | |||||
| 言語 | en | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| 資源タイプ | ||||||
| 資源 | http://purl.org/coar/resource_type/c_6501 | |||||
| タイプ | departmental bulletin paper | |||||
| 著者 |
Tohru, KANNO
× Tohru, KANNO× Yukitoshi, TATSUMOTO× Masayoshi, KOBAYASHI |
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| 抄録 | ||||||
| 内容記述タイプ | Abstract | |||||
| 内容記述 | The kinetics of the hydration of propene on a Solid Polymer Electrolyte (SPE) and a silver-supported one have been studied by using the steady state and unsteady state methods at a temperature range of 100?160℃, using an ordinary now reactor under atmospheric pressure. The reaction gave two products in parallel reaction, iso-propylalcohol and hexane, and the reaction rates are represented as follows γ_<PγOH>=κPc_3H_6PH_2O^m andγ_<hex>=κPc_3H_6PH_2O^n with activation energies 46 and 90 kJ/mol, respectively. All the transient response curves caused by the concentration jump of propene gave a monotonic mode suggesting a Langmuir-Hinshelwood mechanism with the rate controlling step of carbenium ion formation. | |||||
| 言語 | en | |||||
| 書誌情報 |
ja : 北見工業大学研究報告 巻 21, 号 1, p. 81-95, 発行日 1989-11 |
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| フォーマット | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | application/pdf | |||||
| 著者版フラグ | ||||||
| 言語 | en | |||||
| 値 | publisher | |||||
| 出版者 | ||||||
| 出版者 | 北見工業大学 | |||||
| 言語 | ja | |||||
