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  1. 紀要掲載論文
  2. 北見工業大学研究報告
  3. Vol.21

Kinetics of Gas-Phase Hydration of Propene Heterogeneously Catalysed on a Solid Polymer Electrolyte*

https://kitami-it.repo.nii.ac.jp/records/6649
4d3bbf8f-360a-4fdc-b61b-b5e0bf4e5f22
名前 / ファイル ライセンス アクション
21-1-6.pdf 21-1-6.pdf (5.5 MB)
Item type 紀要論文 / Departmental Bulletin Paper(1)
公開日 2007-04-09
タイトル
タイトル Kinetics of Gas-Phase Hydration of Propene Heterogeneously Catalysed on a Solid Polymer Electrolyte*
言語
言語 eng
資源タイプ
資源 http://purl.org/coar/resource_type/c_6501
タイプ departmental bulletin paper
著者 Tohru, KANNO

× Tohru, KANNO

WEKO 33580

Tohru, KANNO

Search repository
Yukitoshi, TATSUMOTO

× Yukitoshi, TATSUMOTO

WEKO 33581

Yukitoshi, TATSUMOTO

Search repository
Masayoshi, KOBAYASHI

× Masayoshi, KOBAYASHI

WEKO 33582

Masayoshi, KOBAYASHI

Search repository
抄録
内容記述タイプ Abstract
内容記述 The kinetics of the hydration of propene on a Solid Polymer Electrolyte (SPE) and a silver-supported one have been studied by using the steady state and unsteady state methods at a temperature range of 100?160℃, using an ordinary now reactor under atmospheric pressure. The reaction gave two products in parallel reaction, iso-propylalcohol and hexane, and the reaction rates are represented as follows γ_<PγOH>=κPc_3H_6PH_2O^m andγ_<hex>=κPc_3H_6PH_2O^n with activation energies 46 and 90 kJ/mol, respectively. All the transient response curves caused by the concentration jump of propene gave a monotonic mode suggesting a Langmuir-Hinshelwood mechanism with the rate controlling step of carbenium ion formation.
書誌情報 北見工業大学研究報告

巻 21, 号 1, p. 81-95, 発行日 1989-11
フォーマット
内容記述タイプ Other
内容記述 application/pdf
著者版フラグ
値 publisher
出版者
出版者 北見工業大学
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