{"_buckets": {"deposit": "694335de-8f19-43ae-bd23-2d2b98e8c53f"}, "_deposit": {"id": "6595", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "6595"}, "status": "published"}, "_oai": {"id": "oai:kitami-it.repo.nii.ac.jp:00006595"}, "item_2_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "1986-11", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "1", "bibliographicPageEnd": "62", "bibliographicPageStart": "45", "bibliographicVolumeNumber": "18", "bibliographic_titles": [{"bibliographic_title": "\u5317\u898b\u5de5\u696d\u5927\u5b66\u7814\u7a76\u5831\u544a"}]}]}, "item_2_description_14": {"attribute_name": "\u30d5\u30a9\u30fc\u30de\u30c3\u30c8", "attribute_value_mlt": [{"subitem_description": "application/pdf", "subitem_description_type": "Other"}]}, "item_2_description_4": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "The dynamic adsorption behavior of O_2, CO and CO_2 on MgO and MgCO_3 has been studied in detail at temperatures ranging from 150 to 171\u2103, by using the transient response method. 0n MgCO_3 no CO adsorbs and no CO oxidation proceeds. CO_2 is reversibly adsorbed obeying the Langmuir isotherm and the heat of adsorption is evaluated to be 2.7kcal/mol. On MgO, on the other hand, no CO adsorbs whereas the oxidation of CO easily proceeds and the rate equation is expressed : \u03b3=kPco^\u003c0.63\u003ePo_2^\u003c0.29\u003e The apparent activation energy of reaction is estimated to be 14.6 kcal/mol. CO_2, adsorbs on the surface in both the reversible and irreversible forms. The reversibly adsorbed CO_2 has 4.3 kcal/mol of activation energy for adsorption and 13 kcal/mol for desorption. The irreversibly adsorbed CO_2 can partly desorb by elevating the temperature. A large part of the surface is covered with the strongly adsorbed CO_2, the surface coverage of which is 0.86. Only a small part of the active sites (\u03b8=4.2\u00d710^\u003c-4\u003e) is available for the adsorption of oxygen and one fifth of the amount is irreversible. The mode of the transient response curves obtained in the oxidation of CO indicates a typical monotone type suggesting that the reaction rate is controlled by the surface reaction and the desorptipon of CO_2.\u3000\u3000", "subitem_description_type": "Abstract"}]}, "item_2_publisher_32": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "\u5317\u898b\u5de5\u696d\u5927\u5b66"}]}, "item_2_select_15": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "publisher"}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Yasuyuki, KONISHI"}], "nameIdentifiers": [{"nameIdentifier": "33211", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Toshio, KATAGIRI"}], "nameIdentifiers": [{"nameIdentifier": "33212", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Shichi, YASUI"}], "nameIdentifiers": [{"nameIdentifier": "33213", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Yoshinori, NAKANISHI"}], "nameIdentifiers": [{"nameIdentifier": "33214", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Tohru, KANNO"}], "nameIdentifiers": [{"nameIdentifier": "33215", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Masayoshi, KOBAYASHI"}], "nameIdentifiers": [{"nameIdentifier": "33216", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2016-11-22"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "18-1-4.pdf", "filesize": [{"value": "7.2 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 7200000.0, "url": {"label": "18-1-4.pdf", "url": "https://kitami-it.repo.nii.ac.jp/record/6595/files/18-1-4.pdf"}, "version_id": "f78fb488-7c5c-4b50-badb-0d046945e32a"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "departmental bulletin paper", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Transient Characterization of Carbon Monoxide, Carbon Dioxide and Oxygen Adsorbed on MgO and MgCO_3*", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Transient Characterization of Carbon Monoxide, Carbon Dioxide and Oxygen Adsorbed on MgO and MgCO_3*"}]}, "item_type_id": "2", "owner": "1", "path": ["7/15/39"], "permalink_uri": "https://kitami-it.repo.nii.ac.jp/records/6595", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_value": "2007-04-09"}, "publish_date": "2007-04-09", "publish_status": "0", "recid": "6595", "relation": {}, "relation_version_is_last": true, "title": ["Transient Characterization of Carbon Monoxide, Carbon Dioxide and Oxygen Adsorbed on MgO and MgCO_3*"], "weko_shared_id": 3}