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  1. 紀要掲載論文
  2. 北見工業大学研究報告
  3. Vol.8

水の液体構造と水溶液中の溶質-溶媒間相互作用(第2報) : 溶質-溶媒間相互作用

https://kitami-it.repo.nii.ac.jp/records/6422
593d0f27-77d3-482a-8880-99ddca784970
名前 / ファイル ライセンス アクション
8-2-5.pdf 8-2-5.pdf (6.7 MB)
Item type 紀要論文 / Departmental Bulletin Paper(1)
公開日 2007-04-09
タイトル
タイトル 水の液体構造と水溶液中の溶質-溶媒間相互作用(第2報) : 溶質-溶媒間相互作用
言語
言語 jpn
資源タイプ
資源 http://purl.org/coar/resource_type/c_6501
タイプ departmental bulletin paper
その他のタイトル
その他のタイトル The Structure of Water and Solute-Solvent Interactions in Aqueous Solutions (Part 2) : Solute-Solvent Interaction
著者 佐々木, 克孝

× 佐々木, 克孝

WEKO 32527

佐々木, 克孝

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著者別名
識別子
識別子 32528
識別子Scheme WEKO
姓名
姓名 SASAKI, Katsutaka
抄録
内容記述タイプ Abstract
内容記述 The influences of various solute molecules upon the structure of water have been investigated by means of the ultrasonic pulse technique.  It is shown that typical protein denaturants such as urea and guanidine hydrochloride behave as a structure breaker of the water structure. This effect of the denaturants is closely related to the denaturing process of protein molecules in water.  The effects of alkyl-substituted ureas upon the water structure have been studied in order to obtain information on hydrocarbon-water interactions. 1,3-Dimethylurea molecules behave as a weak structure breaker, but 1,3-diethylurea molecules behave as a structure former in water. The solute-solvent interactions in aqueous solutions of tetramethylurea are essentially similar to that of 1, 3-dimethylurea solutions in low concentrations.  The behavior of several neutral amino acids in water is similar to each other, irrespective of their difference of size of alkyl groups contained in solute molecules. It is said that neutral amino acids can not be used as a model for studying the iceberg formation. In the case of aqueous diamine solutions, the iceberg formation around hydrocarbon groups become appreciable at the carbon number 3 in solute molecules.It is concluded that the structure of icebergs formed in dimine solutions is more dense and stable than that of the ice-like structure in bulk water.
書誌情報 北見工業大学研究報告

巻 8, 号 2, p. 181-196, 発行日 1977-03
フォーマット
内容記述タイプ Other
内容記述 application/pdf
著者版フラグ
値 publisher
出版者
出版者 北見工業大学
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