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水の液体構造と水溶液中の溶質－溶媒間相互作用（第１報） : 水の液体構造
https://kitami-it.repo.nii.ac.jp/records/6410
https://kitami-it.repo.nii.ac.jp/records/6410a9f4d313-a27f-4ddd-9618-eb13537df5f5
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
8-1-6.pdf (6.9 MB)
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| Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||
|---|---|---|---|---|---|---|
| 公開日 | 2007-04-09 | |||||
| タイトル | ||||||
| タイトル | 水の液体構造と水溶液中の溶質－溶媒間相互作用（第１報） : 水の液体構造 | |||||
| 言語 | ja | |||||
| 言語 | ||||||
| 言語 | jpn | |||||
| 資源タイプ | ||||||
| 資源 | http://purl.org/coar/resource_type/c_6501 | |||||
| タイプ | departmental bulletin paper | |||||
| その他のタイトル | ||||||
| その他のタイトル | The Structure of Water and Solute-Solvent Interactions in Aqueous Solutions（Part 1） : The Structure of Water | |||||
| 言語 | en | |||||
| 著者 |
佐々木, 克孝
× 佐々木, 克孝 |
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| 著者別名 | ||||||
| 識別子Scheme | WEKO | |||||
| 識別子 | 32488 | |||||
| 姓名 | SASAKI, Katsutaka | |||||
| 言語 | en | |||||
| 抄録 | ||||||
| 内容記述タイプ | Abstract | |||||
| 内容記述 | Thermodynamic properties were calculated based on the simple two-state model (ice-like structure and close-packed structure), which was proposed by Hall. The results obtained were fairly good in agreement with the experimental data. The same procedure was applied to liquid deuterium oxide in order to investigate the applicability of the two-state model. From the results obtained, we can conclude that the two-state model gives an adequate representation of the thermodynamic properties of liquid water. In the constitution of the two-state theory, we had no regard for the cooperative nature of hydrogen-bond formation and breaking. The cooperative nature is one of the most important features of the structure of water. Therefore, the order-disorder theory was applied to the structure theory of water with the intention of considering that nature. We can constitute a statistical thermodynamic theory without any adjustable parameters, using the Bragg-Williams approximation. The agreements between calculated values and observed ones are good. Hydrogen-bond energy in this theory decreases continuously with increasing temperature. This aspect is a reflection of the cooperative nature of the structure of water. | |||||
| 言語 | en | |||||
| 書誌情報 |
ja : 北見工業大学研究報告 巻 8, 号 1, p. 65-81, 発行日 1976-11 |
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| フォーマット | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | application/pdf | |||||
| 著者版フラグ | ||||||
| 言語 | en | |||||
| 値 | publisher | |||||
| 出版者 | ||||||
| 出版者 | 北見工業大学 | |||||
| 言語 | ja | |||||
