{"_buckets": {"deposit": "285e0321-211e-4e74-b496-a1fb2e6cf303"}, "_deposit": {"id": "6181", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "6181"}, "status": "published"}, "_oai": {"id": "oai:kitami-it.repo.nii.ac.jp:00006181"}, "item_2_alternative_title_18": {"attribute_name": "\u305d\u306e\u4ed6\u306e\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_alternative_title": "The Reaction of Peat Humic Acid with Epychlorohydrin"}]}, "item_2_biblio_info_6": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "1966-03", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "4", "bibliographicPageEnd": "84", "bibliographicPageStart": "77", "bibliographicVolumeNumber": "1", "bibliographic_titles": [{"bibliographic_title": "\u5317\u898b\u5de5\u696d\u5927\u5b66\u7814\u7a76\u5831\u544a"}]}]}, "item_2_description_14": {"attribute_name": "\u30d5\u30a9\u30fc\u30de\u30c3\u30c8", "attribute_value_mlt": [{"subitem_description": "application/pdf", "subitem_description_type": "Other"}]}, "item_2_description_4": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "The reaction of peat humic acid in NaOH aq. with epychlorohydrin had been studied. The conditions of reaction were as follows : the reaction temp. was 70\u2103 ; the reaction time was about 50?60 minutes ; the end point of reaction was recognized immediately after the gelatinized\u3000\uff4dass\u3000vvas\u3000obtained.\u3000Whether or not the reaction was completed was\u3000detected by aids of infrared spectra and other analyses. Natural humic\u3000acid being used, the highest yield was about 74\uff05 on the ratio of  1 mol. sodium hydroxide to 4 mol. epychlorohydrin with 150 g humic acid, and epoxy O\uff05 was about 6.5. In the case of using ZnCl_2, SnCl_2 and SnCl_4  as a catalyst, the reaction time was about 30 minutes, but yields and epoxy O\uff05 were not increased.\u3000And reactants of the above case did not react to a sclerotic, and were insoluble in any solvents. The oxidized humic acid being used, the resin \uff08softening point was about 60\u2103\uff09 was obtained by the hardening reaction with ethylenediamine", "subitem_description_type": "Abstract"}]}, "item_2_full_name_3": {"attribute_name": "\u8457\u8005\u5225\u540d", "attribute_value_mlt": [{"nameIdentifiers": [{"nameIdentifier": "31689", "nameIdentifierScheme": "WEKO"}], "names": [{"name": "Mitsuo, SASAKl"}]}, {"nameIdentifiers": [{"nameIdentifier": "31690", "nameIdentifierScheme": "WEKO"}], "names": [{"name": "Hiroshi, OKA"}]}]}, "item_2_publisher_32": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "\u5317\u898b\u5de5\u696d\u5927\u5b66"}]}, "item_2_select_15": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "publisher"}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "\u4f50\u3005\u6728, \u6e80\u96c4"}], "nameIdentifiers": [{"nameIdentifier": "31687", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "\u5ca1, \u5b8f"}], "nameIdentifiers": [{"nameIdentifier": "31688", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2016-11-22"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "1-4-9.pdf", "filesize": [{"value": "2.9 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 2900000.0, "url": {"label": "1-4-9.pdf", "url": "https://kitami-it.repo.nii.ac.jp/record/6181/files/1-4-9.pdf"}, "version_id": "8d031b25-1444-4c32-852b-bd984bef9cce"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "jpn"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "departmental bulletin paper", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "\u6ce5\u70ad\u30d5\u30df\u30f3\u9178\u3068\u30a8\u30d4\u30af\u30ed\u30eb\u30d2\u30c9\u30ea\u30f3\u306e\u53cd\u5fdc", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "\u6ce5\u70ad\u30d5\u30df\u30f3\u9178\u3068\u30a8\u30d4\u30af\u30ed\u30eb\u30d2\u30c9\u30ea\u30f3\u306e\u53cd\u5fdc"}]}, "item_type_id": "2", "owner": "1", "path": ["7/15/21"], "permalink_uri": "https://kitami-it.repo.nii.ac.jp/records/6181", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_value": "2007-04-09"}, "publish_date": "2007-04-09", "publish_status": "0", "recid": "6181", "relation": {}, "relation_version_is_last": true, "title": ["\u6ce5\u70ad\u30d5\u30df\u30f3\u9178\u3068\u30a8\u30d4\u30af\u30ed\u30eb\u30d2\u30c9\u30ea\u30f3\u306e\u53cd\u5fdc"], "weko_shared_id": 3}