{"_buckets": {"deposit": "2b3483ba-95d4-4d51-b9bd-9f7444ea79cf"}, "_deposit": {"created_by": 15, "id": "2000421", "owner": "15", "owners": [15], "owners_ext": {"displayname": "北見工業大学学術機関リポジトリ（KIT-R）", "username": "kitir"}, "pid": {"revision_id": 0, "type": "depid", "value": "2000421"}, "status": "published"}, "_oai": {"id": "oai:kitami-it.repo.nii.ac.jp:02000421"}, "author_link": [], "item_1646810750418": {"attribute_name": "出版タイプ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_970fb48d4fbd8a85", "subitem_version_type": "VoR"}]}, "item_3_biblio_info_186": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2020-10", "bibliographicIssueDateType": "Issued"}, "bibliographicPageEnd": "37587", "bibliographicPageStart": "37582", "bibliographicVolumeNumber": "10", "bibliographic_titles": [{"bibliographic_title": "RSC Advances", "bibliographic_titleLang": "en"}]}]}, "item_3_description_184": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "C–H symmetric stretching vibrational frequencies of CH4, C2H4 and C2H6 molecules encapsulated in 512, 51262 and 51264 cages of structures I (sI) and II (sII) clathrate hydrates measured by Raman spectroscopy in the temperature range of 93–183 K was analysed. The slopes of the symmetric stretch vibrational frequencies under changing temperatures (Δv/ΔT) for CH4, C2H4 and C2H6 molecules encapsulated in sII 51264 cages were smaller than those for molecules in sI 51262 cages, although sI 51262 cages are smaller than sII 51264 cages. We compared the results of Δv/ΔT in this study with the geometrical properties of each host water cage, and these comparisons suggest that the geometry of host water cages affects Δv/ΔT.", "subitem_description_language": "en", "subitem_description_type": "Abstract"}]}, "item_3_publisher_212": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "The Royal Society of Chemistry", "subitem_publisher_language": "en"}]}, "item_3_relation_191": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type_id": {"subitem_relation_type_id_text": "https://doi.org/10.1039/D0RA06668K", "subitem_relation_type_select": "DOI"}}]}, "item_3_rights_192": {"attribute_name": "権利", "attribute_value_mlt": [{"subitem_rights": "© The Royal Society of Chemistry", "subitem_rights_language": "en"}]}, "item_3_select_195": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_select_item": "publisher", "subitem_select_language": "en"}]}, "item_access_right": {"attribute_name": "アクセス権", "attribute_value_mlt": [{"subitem_access_right": "open access", "subitem_access_right_uri": "http://purl.org/coar/access_right/c_abf2"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Go Fuseya", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "Satoshi Takeya", "creatorNameLang": "en"}]}, {"creatorNames": [{"creatorName": "Akihiro Hachikubo", "creatorNameLang": "en"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_access", "date": [{"dateType": "Available", "dateValue": "2023-04-20"}], "download_preview_message": "", "file_order": 0, "filename": "d0ra06668k(1).pdf", "filesize": [{"value": "884 KB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_6", "mimetype": "application/pdf", "size": 884000.0, "url": {"url": "https://kitami-it.repo.nii.ac.jp/record/2000421/files/d0ra06668k(1).pdf"}, "version_id": "7aa96a97-7b76-42a3-9dbe-5d568ad496a4"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Temperature effects on the C–H symmetric stretching vibrational frequencies of guest hydrocarbon molecules in 512, 51262 and 51264 cages of sI and sII clathrate hydrates", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Temperature effects on the C–H symmetric stretching vibrational frequencies of guest hydrocarbon molecules in 512, 51262 and 51264 cages of sI and sII clathrate hydrates", "subitem_title_language": "en"}]}, "item_type_id": "3", "owner": "15", "path": ["87"], "permalink_uri": "https://kitami-it.repo.nii.ac.jp/records/2000421", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2023-04-20"}, "publish_date": "2023-04-20", "publish_status": "0", "recid": "2000421", "relation": {}, "relation_version_is_last": true, "title": ["Temperature effects on the C–H symmetric stretching vibrational frequencies of guest hydrocarbon molecules in 512, 51262 and 51264 cages of sI and sII clathrate hydrates"], "weko_shared_id": -1}