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Generation of bis(pentafluorophenyl)borane-dimethyl sulfide complex as a solution of hexane and its application to hydroboration of alk-1-yne with pinacolborane
https://kitami-it.repo.nii.ac.jp/records/7337
https://kitami-it.repo.nii.ac.jp/records/73378ca8579e-b644-4dd1-b981-9cdbff2d8518
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
168TL-0708-417.pdf (183.8 kB)
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||
|---|---|---|---|---|---|---|
| 公開日 | 2009-03-26 | |||||
| タイトル | ||||||
| タイトル | Generation of bis(pentafluorophenyl)borane-dimethyl sulfide complex as a solution of hexane and its application to hydroboration of alk-1-yne with pinacolborane | |||||
| 言語 | en | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | bis(pentafluorophenyl)borane-dimethyl sulfide complex | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | tris(pentafluorophenyl)borane | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | borane-dimethyl sulfide complex | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | hydroboration | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | pinacolborane | |||||
| 資源タイプ | ||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
| 資源タイプ | journal article | |||||
| アクセス権 | ||||||
| アクセス権 | open access | |||||
| アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||
| 著者 |
HOSHI, Masayuki
× HOSHI, Masayuki× SHIRAKAWA, Kazuya× OKIMOTO, Mitsuhiro |
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| 抄録 | ||||||
| 内容記述タイプ | Abstract | |||||
| 内容記述 | A solution of bis(pentafluorophenyl)borane-dimethyl sulfide complex in hexane was generated by redistribution between tris(pentafluorophenyl)borane and borane-dimethyl sulfide complex. In the resulting solution a stoichiometric hydroboration of alk-1-yne with pinacolborane proceeded well at room temperature to afford (E)-alk-1-enylboronic acid pinacol ester in high yield. Bis(pentafluorophenyl)borane-dimethyl sulfide complex served as a mediator for the hydroboration. | |||||
| 内容記述 | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | Copyright c 2007 Elsevier Ltd All rights reserved. | |||||
| 書誌情報 |
Tetrahedron Letters 巻 48, 号 48, p. 8475-8478, 発行日 2007-11 |
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| DOI | ||||||
| 識別子タイプ | DOI | |||||
| 関連識別子 | http://doi.org/10.1016/j.tetlet.2007.09.176 | |||||
| フォーマット | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | application/pdf | |||||
| 出版者 | ||||||
| 出版者 | Elsevier | |||||
| 著者版フラグ | ||||||
| 値 | author | |||||
| 出版タイプ | ||||||
| 出版タイプ | AM | |||||
| 出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
