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  1. 学術雑誌掲載済論文
  2. 和雑誌

Generation of bis(pentafluorophenyl)borane-dimethyl sulfide complex as a solution of hexane and its application to hydroboration of alk-1-yne with pinacolborane

https://kitami-it.repo.nii.ac.jp/records/7337
8ca8579e-b644-4dd1-b981-9cdbff2d8518
名前 / ファイル ライセンス アクション
168TL-0708-417.pdf 168TL-0708-417.pdf (183.8 kB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2009-03-26
タイトル
言語 en
タイトル Generation of bis(pentafluorophenyl)borane-dimethyl sulfide complex as a solution of hexane and its application to hydroboration of alk-1-yne with pinacolborane
言語
言語 eng
キーワード
主題Scheme Other
主題 bis(pentafluorophenyl)borane-dimethyl sulfide complex
キーワード
主題Scheme Other
主題 tris(pentafluorophenyl)borane
キーワード
主題Scheme Other
主題 borane-dimethyl sulfide complex
キーワード
主題Scheme Other
主題 hydroboration
キーワード
主題Scheme Other
主題 pinacolborane
資源タイプ
資源 http://purl.org/coar/resource_type/c_6501
タイプ journal article
アクセス権
アクセス権 open access
アクセス権URI http://purl.org/coar/access_right/c_abf2
著者 HOSHI, Masayuki

× HOSHI, Masayuki

WEKO 37458

en HOSHI, Masayuki

Search repository
SHIRAKAWA, Kazuya

× SHIRAKAWA, Kazuya

WEKO 37459

en SHIRAKAWA, Kazuya

Search repository
OKIMOTO, Mitsuhiro

× OKIMOTO, Mitsuhiro

WEKO 37460

en OKIMOTO, Mitsuhiro

Search repository
抄録
内容記述タイプ Abstract
内容記述 A solution of bis(pentafluorophenyl)borane-dimethyl sulfide complex in hexane was generated by redistribution between tris(pentafluorophenyl)borane and borane-dimethyl sulfide complex. In the resulting solution a stoichiometric hydroboration of alk-1-yne with pinacolborane proceeded well at room temperature to afford (E)-alk-1-enylboronic acid pinacol ester in high yield. Bis(pentafluorophenyl)borane-dimethyl sulfide complex served as a mediator for the hydroboration.
内容記述
内容記述タイプ Other
内容記述 Copyright c 2007 Elsevier Ltd All rights reserved.
書誌情報 Tetrahedron Letters

巻 48, 号 48, p. 8475-8478, 発行日 2007-11
DOI
関連識別子
識別子タイプ DOI
関連識別子 http://doi.org/10.1016/j.tetlet.2007.09.176
フォーマット
内容記述タイプ Other
内容記述 application/pdf
出版者
出版者 Elsevier
著者版フラグ
値 author
出版タイプ
出版タイプ AM
出版タイプResource http://purl.org/coar/version/c_ab4af688f83e57aa
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