{"_buckets": {"deposit": "4bd4ba20-5816-4889-8274-ae673a32282f"}, "_deposit": {"id": "7337", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "7337"}, "status": "published"}, "_oai": {"id": "oai:kitami-it.repo.nii.ac.jp:00007337"}, "item_3_biblio_info_186": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2007-11", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "48", "bibliographicPageEnd": "8478", "bibliographicPageStart": "8475", "bibliographicVolumeNumber": "48", "bibliographic_titles": [{"bibliographic_title": "Tetrahedron Letters"}]}]}, "item_3_description_184": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "A solution of bis(pentafluorophenyl)borane-dimethyl sulfide complex in hexane was generated by redistribution between tris(pentafluorophenyl)borane and borane-dimethyl sulfide complex. In the resulting solution a stoichiometric hydroboration of alk-1-yne with pinacolborane proceeded well at room temperature to afford (E)-alk-1-enylboronic acid pinacol ester in high yield. Bis(pentafluorophenyl)borane-dimethyl sulfide complex served as a mediator for the hydroboration.", "subitem_description_type": "Abstract"}]}, "item_3_description_185": {"attribute_name": "\u5185\u5bb9\u8a18\u8ff0", "attribute_value_mlt": [{"subitem_description": "Copyright c 2007 Elsevier Ltd All rights reserved.", "subitem_description_type": "Other"}]}, "item_3_description_194": {"attribute_name": "\u30d5\u30a9\u30fc\u30de\u30c3\u30c8", "attribute_value_mlt": [{"subitem_description": "application/pdf", "subitem_description_type": "Other"}]}, "item_3_publisher_212": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "Elsevier"}]}, "item_3_relation_191": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type_id": {"subitem_relation_type_id_text": "http://doi.org/10.1016/j.tetlet.2007.09.176", "subitem_relation_type_select": "DOI"}}]}, "item_3_select_195": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "HOSHI, Masayuki"}], "nameIdentifiers": [{"nameIdentifier": "37458", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "SHIRAKAWA, Kazuya"}], "nameIdentifiers": [{"nameIdentifier": "37459", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "OKIMOTO, Mitsuhiro"}], "nameIdentifiers": [{"nameIdentifier": "37460", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2016-11-22"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "168TL-0708-417.pdf", "filesize": [{"value": "183.8 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 183800.0, "url": {"label": "168TL-0708-417.pdf", "url": "https://kitami-it.repo.nii.ac.jp/record/7337/files/168TL-0708-417.pdf"}, "version_id": "69e9f2a5-d3fb-42b4-910c-b4887ce9b4dd"}]}, "item_keyword": {"attribute_name": "\u30ad\u30fc\u30ef\u30fc\u30c9", "attribute_value_mlt": [{"subitem_subject": "bis(pentafluorophenyl)borane-dimethyl sulfide complex", "subitem_subject_scheme": "Other"}, {"subitem_subject": "tris(pentafluorophenyl)borane", "subitem_subject_scheme": "Other"}, {"subitem_subject": "borane-dimethyl sulfide complex", "subitem_subject_scheme": "Other"}, {"subitem_subject": "hydroboration", "subitem_subject_scheme": "Other"}, {"subitem_subject": "pinacolborane", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Generation of bis(pentafluorophenyl)borane-dimethyl sulfide complex as a solution of hexane and its application to hydroboration of alk-1-yne with pinacolborane", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Generation of bis(pentafluorophenyl)borane-dimethyl sulfide complex as a solution of hexane and its application to hydroboration of alk-1-yne with pinacolborane"}]}, "item_type_id": "3", "owner": "1", "path": ["1"], "permalink_uri": "https://kitami-it.repo.nii.ac.jp/records/7337", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_value": "2009-03-26"}, "publish_date": "2009-03-26", "publish_status": "0", "recid": "7337", "relation": {}, "relation_version_is_last": true, "title": ["Generation of bis(pentafluorophenyl)borane-dimethyl sulfide complex as a solution of hexane and its application to hydroboration of alk-1-yne with pinacolborane"], "weko_shared_id": 3}