{"created":"2021-03-01T05:59:37.443220+00:00","id":7173,"links":{},"metadata":{"_buckets":{"deposit":"781dcb79-0b67-40f1-9681-c3578286d15c"},"_deposit":{"id":"7173","owners":[],"pid":{"revision_id":0,"type":"depid","value":"7173"},"status":"published"},"_oai":{"id":"oai:kitami-it.repo.nii.ac.jp:00007173","sets":["1:87"]},"author_link":["44871","36495","36496","36497"],"item_1646810750418":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_3_biblio_info_186":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2005-08","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"12","bibliographicPageEnd":"2007","bibliographicPageStart":"1991","bibliographicVolumeNumber":"2005","bibliographic_titles":[{"bibliographic_title":"Synthesis"}]}]},"item_3_description_184":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Both 1-arylalk-3-en-1-yne and alka-1,5-dien-3-yne have been synthesized under extremely mild reaction conditions in good to high yields via a sequential Suzuki-type and Sonogashira reaction in a one-pot manner. Thus, the protocol involves Cumediated cross-coupling reaction of (E)- or (Z)- alkenyldisiamylborane with (trimethylsilyl)ethynyl bromide in the presence of 1M-NaOMe and Pd/Cu-catalyzed cross-coupling reaction with aryl or alkenyl iodide in the presence of aqueous n-Bu4NOH. The reaction with aryl iodide is tolerant of a wide variety of functional groups on the aromatic ring and leads to the stereoselective formation of (E)- and (Z)-1-arylalk-3-en-1-ynes. In addition, the reactions with (E)- and (Z)-1-iodoalk-1-enes have accomplished the construction of all possible combinations of geometrical isomers, (E,E)-, (Z,E)-, (E,Z)-, and (Z,Z)- alka-1,5-dien-3-ynes.","subitem_description_type":"Abstract"}]},"item_3_description_194":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_3_full_name_183":{"attribute_name":"著者別名","attribute_value_mlt":[{"nameIdentifiers":[{"nameIdentifier":"44871","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"113712","nameIdentifierScheme":"KAKEN","nameIdentifierURI":"https://nrid.nii.ac.jp/ja/nrid/1000000113712 "}],"names":[{"name":"星, 雅之","nameLang":"ja"}]}]},"item_3_publisher_212":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Georg Thieme Verlag"}]},"item_3_relation_191":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"http://doi.org/10.1055/s-2005-869955","subitem_relation_type_select":"DOI"}}]},"item_3_rights_192":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"http://www.thieme-connect.de/ejournals/abstract/synthesis/doi/10.1055/s-2005-869955"},{"subitem_rights":"Georg Thieme Verlag, M.Hoshi, H.Nakayabu, K.Shirakawa, Synthesis, 2005(12), 2005, 1991-2007. c 2005 Georg Thieme Verlag KG."}]},"item_3_select_195":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"author"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Hoshi, Masayuki","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Nakayabu, Hidenori","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"Shirakawa, Kazuya","creatorNameLang":"en"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2016-11-22"}],"displaytype":"detail","filename":"4613.pdf","filesize":[{"value":"175.5 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"4613.pdf","url":"https://kitami-it.repo.nii.ac.jp/record/7173/files/4613.pdf"},"version_id":"e075dd6b-56f6-4630-b472-981528df05bc"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Stereoselective Syntheses of (E)- and (Z)-1-Arylalk-3-en-1-ynes and (E,E)-, (Z,E)-, (E,Z)-, and (Z,Z)-Alka-1,5-dien-3-ynes via a One-pot Multicomponent Coupling Reaction.","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Stereoselective Syntheses of (E)- and (Z)-1-Arylalk-3-en-1-ynes and (E,E)-, (Z,E)-, (E,Z)-, and (Z,Z)-Alka-1,5-dien-3-ynes via a One-pot Multicomponent Coupling Reaction.","subitem_title_language":"en"}]},"item_type_id":"3","owner":"1","path":["87"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2007-05-11"},"publish_date":"2007-05-11","publish_status":"0","recid":"7173","relation_version_is_last":true,"title":["Stereoselective Syntheses of (E)- and (Z)-1-Arylalk-3-en-1-ynes and (E,E)-, (Z,E)-, (E,Z)-, and (Z,Z)-Alka-1,5-dien-3-ynes via a One-pot Multicomponent Coupling Reaction."],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2022-12-13T02:24:58.475463+00:00"}