{"_buckets": {"deposit": "2b56042f-1d92-4c2c-a974-7f218f92591f"}, "_deposit": {"id": "7172", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "7172"}, "status": "published"}, "_oai": {"id": "oai:kitami-it.repo.nii.ac.jp:00007172"}, "item_3_biblio_info_186": {"attribute_name": "\u66f8\u8a8c\u60c5\u5831", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2006-06", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "12", "bibliographicPageEnd": "1970", "bibliographicPageStart": "1961", "bibliographicVolumeNumber": "2006", "bibliographic_titles": [{"bibliographic_title": "Synlett"}]}]}, "item_3_description_184": {"attribute_name": "\u6284\u9332", "attribute_value_mlt": [{"subitem_description": "The cross-coupling reaction of (E)- and (Z)-alk-1-enyldialkylborane with (trimethylsilyl)ethynyl bromide proceeds in the presence of a catalytic amount of Cu(acac)_2 and a base under extremely mild conditions to provide conjugated enynes whose carbon-carbon triple bond is distal position. The use of 1M NaOMe as the base results in not only cross-coupling but also desilylation affording both (E)- and (Z)-alk-3-en-1-ynes exclusively, while the use of LiOH\uff65H_2O instead of 1M NaOMe preferentially gives both (E)- and (Z)-1-(trimethylsilyl)alk-3-en-1-ynes with high regio- and stereoselectivity. On the other hand, the cross-coupling reaction of (Z)-1-(trimethylsilyl)alk-1-enyldicyclohexylborane with (trimethylsilyl)ethynyl bromide proceeds in the presence of a small amount of CuI and aqueous NaOH under extremely mild conditions to afford (Z)-1,3-bis(trimethylsilyl)alk-3-en-1-yne with high regio- and stereoselectivity. In addition, treatment of the resultant product with 1M NaOMe leads to the stereoselective formation of (Z)-3-(trimethylsilyl)alk-3-en-1-yne in a one-pot manner.", "subitem_description_type": "Abstract"}]}, "item_3_description_194": {"attribute_name": "\u30d5\u30a9\u30fc\u30de\u30c3\u30c8", "attribute_value_mlt": [{"subitem_description": "application/pdf", "subitem_description_type": "Other"}]}, "item_3_full_name_183": {"attribute_name": "\u8457\u8005\u5225\u540d", "attribute_value_mlt": [{"nameIdentifiers": [{"nameIdentifier": "44871", "nameIdentifierScheme": "WEKO"}, {"nameIdentifier": "1000000113712 ", "nameIdentifierScheme": "NRID", "nameIdentifierURI": "http://rns.nii.ac.jp/d/nr/1000000113712 "}], "names": [{"name": "\u661f, \u96c5\u4e4b"}]}]}, "item_3_publisher_212": {"attribute_name": "\u51fa\u7248\u8005", "attribute_value_mlt": [{"subitem_publisher": "Georg Thieme Verlag"}]}, "item_3_relation_191": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type_id": {"subitem_relation_type_id_text": "http://doi.org/10.1055/s-2006-942373", "subitem_relation_type_select": "DOI"}}]}, "item_3_rights_192": {"attribute_name": "\u6a29\u5229", "attribute_value_mlt": [{"subitem_rights": "http://www.thieme-connect.de/ejournals/abstract/synthesis/doi/10.1055/s-2006-942373"}, {"subitem_rights": "Georg Thieme Verlag, M.Hoshi, K.Shirakawa, Synlett, 2006(12), 2006, 1961-1970.  c 2006 Georg Thieme Verlag KG."}]}, "item_3_select_195": {"attribute_name": "\u8457\u8005\u7248\u30d5\u30e9\u30b0", "attribute_value_mlt": [{"subitem_select_item": "author"}]}, "item_3_subject_196": {"attribute_name": "\u65e5\u672c\u5341\u9032\u5206\u985e\u6cd5", "attribute_value_mlt": [{"subitem_subject": "437", "subitem_subject_scheme": "NDC"}]}, "item_creator": {"attribute_name": "\u8457\u8005", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Hoshi, Masayuki"}], "nameIdentifiers": [{"nameIdentifier": "36491", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Kawamura, Noritsugu"}], "nameIdentifiers": [{"nameIdentifier": "36492", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Shirakawa, Kazuya"}], "nameIdentifiers": [{"nameIdentifier": "36493", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "\u30d5\u30a1\u30a4\u30eb\u60c5\u5831", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2016-11-22"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "5113.pdf", "filesize": [{"value": "348.1 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 348100.0, "url": {"label": "5113.pdf", "url": "https://kitami-it.repo.nii.ac.jp/record/7172/files/5113.pdf"}, "version_id": "2c60cd58-fcd7-44f7-983b-b745734db6e8"}]}, "item_language": {"attribute_name": "\u8a00\u8a9e", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "\u8cc7\u6e90\u30bf\u30a4\u30d7", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Construction of Terminal Conjugated Enynes: Cu-Mediated Cross-Coupling Reaction of Alkenyldialkylborane with (Trimethylsilyl)ethynyl Bromide", "item_titles": {"attribute_name": "\u30bf\u30a4\u30c8\u30eb", "attribute_value_mlt": [{"subitem_title": "Construction of Terminal Conjugated Enynes: Cu-Mediated Cross-Coupling Reaction of Alkenyldialkylborane with (Trimethylsilyl)ethynyl Bromide"}]}, "item_type_id": "3", "owner": "1", "path": ["1"], "permalink_uri": "https://kitami-it.repo.nii.ac.jp/records/7172", "pubdate": {"attribute_name": "\u516c\u958b\u65e5", "attribute_value": "2007-05-11"}, "publish_date": "2007-05-11", "publish_status": "0", "recid": "7172", "relation": {}, "relation_version_is_last": true, "title": ["Construction of Terminal Conjugated Enynes: Cu-Mediated Cross-Coupling Reaction of Alkenyldialkylborane with (Trimethylsilyl)ethynyl Bromide"], "weko_shared_id": 3}