@article{oai:kitami-it.repo.nii.ac.jp:00006712,
 author = {木村, 達也 and 城岡, 哲也 and 菅野, 亨 and 小林, 正義},
 issue = {2},
 journal = {北見工業大学研究報告},
 month = {Feb},
 note = {application/pdf, A new membrane reactor has been developed for the oxidative coupling reaction of　methane.　The reactor has been characterized on its activity and selectivity to C_2一production. A porous ceramic membrane tube （α-Al_2O_3，d＝14000Å，φ＝10mm，L＝10cm）is used for the reactor and an La/MgO-catalyst is supported into pores in the membrane by an impregnation technique. The pore size of the membrane could be reduced up to 1000Å, by increasing the number of impregnations. Effective gas separation appears around a pore diameter of 3000Å and C_2-selectivity enhancement is also initiated at the same pore size.　The highest C_2-selectivity is 18％with a catalyst of La/Mg＝0.01 and a temperature of 850℃.},
 pages = {247--256},
 title = {膜反応器における細孔構造制御とメタン酸化カップリング反応},
 volume = {25},
 year = {1994}
}