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Gas Diffusion Process in a Silver Catalyst Used for Ethylene Oxidation*
https://kitami-it.repo.nii.ac.jp/records/6637
https://kitami-it.repo.nii.ac.jp/records/663779bfd6fe-ee02-4d88-af6f-aef946fb086e
名前 / ファイル | ライセンス | アクション |
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Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||
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公開日 | 2007-04-09 | |||||
タイトル | ||||||
タイトル | Gas Diffusion Process in a Silver Catalyst Used for Ethylene Oxidation* | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源 | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | departmental bulletin paper | |||||
著者 |
Tohru, KANNO
× Tohru, KANNO× Masayoshi, KOBAYASHI |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | The diffusion processes of N_2, He, CO_2, C_2H_4 and C_3H_6 in a silver catalyst for ethylene partial oxidation have been studied with a steady state diaphragm cell method using an atomospheric flow system at 30?180℃, relating to ethylene oxidation. Three different catalyst surfaces were prepared as oxidized (S_<OX>), reduced (S_<red>) and treated with ethylene (S_<In>) on which the stable intermediate (In) were accumulated, compared among the effective diffusivities of the gases (De). The molecular diffusion process was achieved with N_2 and He for all the surfaces and at all the gases except O_2 on S_<red>. The De’s of CO_2, C_2H_4 and C_3H_6 on S_<In>. were higher than those on S_<red>, suggesting the contribution of surface diffusion on S_<In>. (In) works to increase the amount of isolated surface oxygen species which is available for the adsorption sites of CO_2, C_2H_4 and C_3H_6. This phenomena causes localization of the gases on the surface and change in their surface diffusion rate. | |||||
書誌情報 |
北見工業大学研究報告 巻 20, 号 2, p. 81-92, 発行日 1989-03 |
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フォーマット | ||||||
内容記述タイプ | Other | |||||
内容記述 | application/pdf | |||||
著者版フラグ | ||||||
値 | publisher | |||||
出版者 | ||||||
出版者 | 北見工業大学 |