@article{oai:kitami-it.repo.nii.ac.jp:00006562, author = {Tohru, KANNO and Masayoshi, KOBAYASHI}, issue = {2}, journal = {北見工業大学研究報告}, month = {Mar}, note = {application/pdf, The diffuse reflectance infrared fouries transform spectroscopy has been applied to directly follow the thermal decomposition of solid silver acetate (CH_3COOA_g). It is found that a two weigt percent of the solid acetate in KB_r powder gives excellent resolutions in an of the spectral region 400-4000 cm^<−1>, compared to resolution from the transmission infrared spectroscopy. The characteristic absorptions hands are almost assigned : 2900-3010 cm^<-1> for C-H stretching modes, 1340 cm^<−1> for CH_3 deformation mode, 1000-1050 cm^<−1> for CH_3-rocking deformation mode, 1575 and 1420 cm^<−1> COO-stretching modes, 620 and 645 cm^<−1> for COO-out of plane rocking deformation and bending mode respectively, and 460 cm^<−1> for in plane COO-rocking deformation mode. The strength of each chracteristic absorption band is commonly and gradually reduced with elevating temperature of the ir cell containing the acetate in the He stream, caused by the gradual decomposition of solid silver acetate. All of the bands disappered by 300℃, indicating the complete decomposition of the acetate to silver, with no residual compounds on the surface.}, pages = {169--175}, title = {Diffuse Reflectance Infrared Fourier Transform Spectra of Solid Silver Acetate*}, volume = {15}, year = {1984} }