{"created":"2021-03-01T05:58:56.994457+00:00","id":6514,"links":{},"metadata":{"_buckets":{"deposit":"0ff5c967-8133-467f-88ef-e8683a98bbd3"},"_deposit":{"id":"6514","owners":[],"pid":{"revision_id":0,"type":"depid","value":"6514"},"status":"published"},"_oai":{"id":"oai:kitami-it.repo.nii.ac.jp:00006514","sets":["7:15:33"]},"item_2_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1981-03","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"2","bibliographicPageEnd":"224","bibliographicPageStart":"221","bibliographicVolumeNumber":"12","bibliographic_titles":[{"bibliographic_title":"北見工業大学研究報告"}]}]},"item_2_description_14":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_2_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The extraction-spectropholometric determination of a trace amount of tetrabutylammonium ion (tba^+) with bis (maleonitriledithiolato) nickelate (II), Ni (mnt)^<2->_2 is described. Ni (mnt)^<2->_2 formed ion-pair with tba^+ and this was quantitatively extracted into chloroform (Kex＝[tba^+_2, Ni (mnt)^<2->_2]_(0)/[Ni (mnt^<2->_2] [tba^+]^2=10^<13.89>]. The molar absorptivity of the ion-pair in chloroform was found to be 2.76×10^4 at 318 nm. Bee's law was confirmed in the range of 0?0.6μmol tba^/10cm~3 CHCL_3. Moderate amounts of most of the anions did not interfere with the determination. This method was also successfully applied to estimation of the ion-pair extraction constant.　　　　　　　　　　　　　　　　　　　","subitem_description_type":"Abstract"}]},"item_2_publisher_32":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"北見工業大学"}]},"item_2_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"publisher"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Sadanobu, INOUE"}],"nameIdentifiers":[{"nameIdentifier":"32886","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"Mitsuo, SASAKI"}],"nameIdentifiers":[{"nameIdentifier":"32887","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2016-11-22"}],"displaytype":"detail","filename":"12-2-8.pdf","filesize":[{"value":"1.8 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"12-2-8.pdf","url":"https://kitami-it.repo.nii.ac.jp/record/6514/files/12-2-8.pdf"},"version_id":"3b230b01-f6e7-4a91-87bc-e5a9000b1f3f"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Spectrophotometric Method for the Determination of Tetrabutylammonium ion*","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Spectrophotometric Method for the Determination of Tetrabutylammonium ion*"}]},"item_type_id":"2","owner":"1","path":["33"],"pubdate":{"attribute_name":"公開日","attribute_value":"2007-04-09"},"publish_date":"2007-04-09","publish_status":"0","recid":"6514","relation_version_is_last":true,"title":["Spectrophotometric Method for the Determination of Tetrabutylammonium ion*"],"weko_creator_id":"1","weko_shared_id":3},"updated":"2022-12-13T02:19:52.500138+00:00"}