{"created":"2021-03-01T05:58:48.790851+00:00","id":6379,"links":{},"metadata":{"_buckets":{"deposit":"5c143802-b6e2-4fad-bcca-b31561ebbac0"},"_deposit":{"id":"6379","owners":[],"pid":{"revision_id":0,"type":"depid","value":"6379"},"status":"published"},"_oai":{"id":"oai:kitami-it.repo.nii.ac.jp:00006379","sets":["7:15:23"]},"item_2_alternative_title_18":{"attribute_name":"その他のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"Reaction of Nitrobenzene with Pentacyanocobaltate (II)"}]},"item_2_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1975-11","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"1","bibliographicPageEnd":"130","bibliographicPageStart":"119","bibliographicVolumeNumber":"7","bibliographic_titles":[{"bibliographic_title":"北見工業大学研究報告"}]}]},"item_2_description_14":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_2_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The reduction of nitrobenzene to azoxybenzene with pentacyanocobaltate(II) complex in aqueous solution was investigated. The active species of the reduction was the hydrido complex 【Co(CN)_5H】^<3?> , which was formed in the homolytic clevage of molecular hydrogen in ordinary temperature but in the clevage of water at elevated temperature. The reaction was pseudo-first order. The activation energy was about 18 kcal/mol.","subitem_description_type":"Abstract"}]},"item_2_full_name_3":{"attribute_name":"著者別名","attribute_value_mlt":[{"nameIdentifiers":[{"nameIdentifier":"32380","nameIdentifierScheme":"WEKO"}],"names":[{"name":"ARAI, Yoshio"}]},{"nameIdentifiers":[{"nameIdentifier":"32381","nameIdentifierScheme":"WEKO"}],"names":[{"name":"MIJIN, Akihiko"}]}]},"item_2_publisher_32":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"北見工業大学"}]},"item_2_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"publisher"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"新井, 義夫"}],"nameIdentifiers":[{"nameIdentifier":"32378","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"見陣, 章彦"}],"nameIdentifiers":[{"nameIdentifier":"32379","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2016-11-22"}],"displaytype":"detail","filename":"7-1-11.pdf","filesize":[{"value":"5.0 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"7-1-11.pdf","url":"https://kitami-it.repo.nii.ac.jp/record/6379/files/7-1-11.pdf"},"version_id":"efbe5e12-0fb2-420c-9f22-10074c95e5c7"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"ペンタシアノコバルト(II)によるニトロベンゼンの還元","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"ペンタシアノコバルト(II)によるニトロベンゼンの還元"}]},"item_type_id":"2","owner":"1","path":["23"],"pubdate":{"attribute_name":"公開日","attribute_value":"2007-04-09"},"publish_date":"2007-04-09","publish_status":"0","recid":"6379","relation_version_is_last":true,"title":["ペンタシアノコバルト(II)によるニトロベンゼンの還元"],"weko_creator_id":"1","weko_shared_id":3},"updated":"2022-12-13T02:19:41.429401+00:00"}