{"created":"2021-03-01T05:58:46.334136+00:00","id":6338,"links":{},"metadata":{"_buckets":{"deposit":"ba48f104-e2ad-482a-bd3f-5dcb2494e34e"},"_deposit":{"id":"6338","owners":[],"pid":{"revision_id":0,"type":"depid","value":"6338"},"status":"published"},"_oai":{"id":"oai:kitami-it.repo.nii.ac.jp:00006338","sets":["7:15:27"]},"item_2_alternative_title_18":{"attribute_name":"その他のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"Selective Reduction of Nitrobenzene by Sodium Borohydride in the presence of several Transition Metal Complexes"}]},"item_2_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1973-10","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"1","bibliographicPageEnd":"77","bibliographicPageStart":"69","bibliographicVolumeNumber":"5","bibliographic_titles":[{"bibliographic_title":"北見工業大学研究報告"}]}]},"item_2_description_14":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_2_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The selective reduction of nitrobenzene to azoxybenzene by NaBH_4 in the presence of several transition metal complexes was investigated at 25°C in an aqueous solution in a nitrogen atmosphere.　The transition metals used were Ni，Cu，Fe(II)，Fe(III)，Mn， Cr and Zn. The ligands used were pyridine，CN^-，acethylacetone，dimethylglyoxime， EDTA and　polyamine， which were　En，Dien，Trien　and Tetren. Ni and Cu were excellent in conversion but inferior to Co， the result of which was reported previously. The reactivity increased in the　following　order :　Co＞Ni＞Cu＞Fe(II).No　reaction occured in the other metals. Polyamine was superior to other ligands in selectivity. In the case of CN^-，azoxybenzene was obtained at 60?70°C. Phenylhydroxylamine was produced in the case of the Cu complex of pyridine or Trien.","subitem_description_type":"Abstract"}]},"item_2_full_name_3":{"attribute_name":"著者別名","attribute_value_mlt":[{"nameIdentifiers":[{"nameIdentifier":"32230","nameIdentifierScheme":"WEKO"}],"names":[{"name":"ARAI, Yoshio"}]}]},"item_2_publisher_32":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"北見工業大学"}]},"item_2_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"publisher"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"新井, 義夫"}],"nameIdentifiers":[{"nameIdentifier":"32228","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"見陣, 章彦"}],"nameIdentifiers":[{"nameIdentifier":"32229","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2016-11-22"}],"displaytype":"detail","filename":"5-1-8.pdf","filesize":[{"value":"3.4 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"5-1-8.pdf","url":"https://kitami-it.repo.nii.ac.jp/record/6338/files/5-1-8.pdf"},"version_id":"0bc2217e-aaad-4338-8b67-ff410edf8d59"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"いくつかの遷移金属錯体と水素化ホウ素ナトリウムによるニトロベンゼンの選択還元","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"いくつかの遷移金属錯体と水素化ホウ素ナトリウムによるニトロベンゼンの選択還元"}]},"item_type_id":"2","owner":"1","path":["27"],"pubdate":{"attribute_name":"公開日","attribute_value":"2007-04-09"},"publish_date":"2007-04-09","publish_status":"0","recid":"6338","relation_version_is_last":true,"title":["いくつかの遷移金属錯体と水素化ホウ素ナトリウムによるニトロベンゼンの選択還元"],"weko_creator_id":"1","weko_shared_id":3},"updated":"2022-12-13T02:19:40.845143+00:00"}