{"created":"2021-03-01T05:58:39.251647+00:00","id":6220,"links":{},"metadata":{"_buckets":{"deposit":"2c6fc946-979c-4e92-be1e-76d02ca1ad33"},"_deposit":{"id":"6220","owners":[],"pid":{"revision_id":0,"type":"depid","value":"6220"},"status":"published"},"_oai":{"id":"oai:kitami-it.repo.nii.ac.jp:00006220","sets":["7:15:22"]},"item_2_alternative_title_18":{"attribute_name":"その他のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"Reduction of Nitrobenzene to Azoxybenzene with the Aqueous Solution of Cobalt (II) Cyanide Complex"}]},"item_2_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1969-02","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"3","bibliographicPageEnd":"377","bibliographicPageStart":"371","bibliographicVolumeNumber":"2","bibliographic_titles":[{"bibliographic_title":"北見工業大学研究報告"}]}]},"item_2_description_14":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_2_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The reduction of nitrobenzene with the aqueous solution of cobalt (II)cyanide complex was carried out in nitrogen atmosphere, and the main product was azoxybenzene. The reaction mechanism was postulated as follows : PhNO_2+2H→PhNO+H_2O (1) PhNO+e→ＰｈＮO^-・ (２) 2(ＰｈＮＯ^-・)→__←O^-/ＰｈＮ-ＮＰｈ/O^- (3) O^-/PhN-NPh+H^+/O^-→PhN=NPh+OH^-/O^- (4) The transfer of electron and the liberation of proton from cobalt cyanide complex result from the above mechanism　","subitem_description_type":"Abstract"}]},"item_2_full_name_3":{"attribute_name":"著者別名","attribute_value_mlt":[{"nameIdentifiers":[{"nameIdentifier":"31808","nameIdentifierScheme":"WEKO"}],"names":[{"name":"Yoshio, ARAl"}]}]},"item_2_publisher_32":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"北見工業大学"}]},"item_2_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"publisher"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"新井, 義夫"}],"nameIdentifiers":[{"nameIdentifier":"31806","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"見陣, 章彦"}],"nameIdentifiers":[{"nameIdentifier":"31807","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2016-11-22"}],"displaytype":"detail","filename":"2-3-2.pdf","filesize":[{"value":"2.6 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"2-3-2.pdf","url":"https://kitami-it.repo.nii.ac.jp/record/6220/files/2-3-2.pdf"},"version_id":"4e1504ea-52fc-43c6-8ed1-fdc427794440"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"シアノコバルト（II）錯体水溶液によるニトロベンゼンのアゾキシベンゼンヘの還元","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"シアノコバルト（II）錯体水溶液によるニトロベンゼンのアゾキシベンゼンヘの還元"}]},"item_type_id":"2","owner":"1","path":["22"],"pubdate":{"attribute_name":"公開日","attribute_value":"2007-04-09"},"publish_date":"2007-04-09","publish_status":"0","recid":"6220","relation_version_is_last":true,"title":["シアノコバルト（II）錯体水溶液によるニトロベンゼンのアゾキシベンゼンヘの還元"],"weko_creator_id":"1","weko_shared_id":3},"updated":"2022-12-13T02:19:33.843793+00:00"}