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シアノコバルト(II)錯体水溶液によるニトロベンゼンのアゾキシベンゼンヘの還元
https://kitami-it.repo.nii.ac.jp/records/6220
https://kitami-it.repo.nii.ac.jp/records/622026a8ca6e-ea98-4962-8f07-3ba4bc7f7be9
名前 / ファイル | ライセンス | アクション |
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Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||
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公開日 | 2007-04-09 | |||||
タイトル | ||||||
タイトル | シアノコバルト(II)錯体水溶液によるニトロベンゼンのアゾキシベンゼンヘの還元 | |||||
言語 | ||||||
言語 | jpn | |||||
資源タイプ | ||||||
資源 | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | departmental bulletin paper | |||||
その他のタイトル | ||||||
その他のタイトル | Reduction of Nitrobenzene to Azoxybenzene with the Aqueous Solution of Cobalt (II) Cyanide Complex | |||||
著者 |
新井, 義夫
× 新井, 義夫× 見陣, 章彦 |
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著者別名 | ||||||
識別子 | 31808 | |||||
識別子Scheme | WEKO | |||||
姓名 | Yoshio, ARAl | |||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | The reduction of nitrobenzene with the aqueous solution of cobalt (II)cyanide complex was carried out in nitrogen atmosphere, and the main product was azoxybenzene. The reaction mechanism was postulated as follows : PhNO_2+2H→PhNO+H_2O (1) PhNO+e→PhNO^-・ (2) 2(PhNO^-・)→__←O^-/PhN-NPh/O^- (3) O^-/PhN-NPh+H^+/O^-→PhN=NPh+OH^-/O^- (4) The transfer of electron and the liberation of proton from cobalt cyanide complex result from the above mechanism | |||||
書誌情報 |
北見工業大学研究報告 巻 2, 号 3, p. 371-377, 発行日 1969-02 |
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フォーマット | ||||||
内容記述タイプ | Other | |||||
内容記述 | application/pdf | |||||
著者版フラグ | ||||||
値 | publisher | |||||
出版者 | ||||||
出版者 | 北見工業大学 |