{"created":"2021-03-01T05:58:39.193790+00:00","id":6219,"links":{},"metadata":{"_buckets":{"deposit":"e354fc13-445a-4324-9287-f5fc8b0e994f"},"_deposit":{"id":"6219","owners":[],"pid":{"revision_id":0,"type":"depid","value":"6219"},"status":"published"},"_oai":{"id":"oai:kitami-it.repo.nii.ac.jp:00006219","sets":["7:15:22"]},"item_2_alternative_title_18":{"attribute_name":"その他のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"The Sulfonation of Peat Humic Acid with Sulfuric Acid-Boron Trifluoride Complex"}]},"item_2_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1969-02","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"3","bibliographicPageEnd":"370","bibliographicPageStart":"365","bibliographicVolumeNumber":"2","bibliographic_titles":[{"bibliographic_title":"北見工業大学研究報告"}]}]},"item_2_description_14":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_2_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The sulfonation of peat humic acid with H_2S0_4-BF_3 complex was studied. The conditions of reaction were as follows. The BF_3/H_2S0_4，mol. ratios were 0.067, 0.134, 0.160, 0.186, 0.210, and 0.235 respectively, the experiments were treated at the reaction time of 10?360 min. and at the temp. of 20?150℃. The ion exchange capacity of sulfonation products was measured by 0.2 N CaCl_2 solution. The results of the above researchs were as follows. The best condition of reaction was shown in the case where BF_3/H_2S0_4 mol. Ratio was 0.134, reaction temp. was 100℃ and that reaction time was 90 min. At this condition of reaction was produced ion exchanger of which ion exchange capacity had been 1.35 m.eq./g.","subitem_description_type":"Abstract"}]},"item_2_full_name_3":{"attribute_name":"著者別名","attribute_value_mlt":[{"nameIdentifiers":[{"nameIdentifier":"31803","nameIdentifierScheme":"WEKO"}],"names":[{"name":"Mitsuo, SASAKI"}]},{"nameIdentifiers":[{"nameIdentifier":"31804","nameIdentifierScheme":"WEKO"}],"names":[{"name":"Hiroshi, OKA"}]},{"nameIdentifiers":[{"nameIdentifier":"31805","nameIdentifierScheme":"WEKO"}],"names":[{"name":"Sadanobu, INOUE"}]}]},"item_2_publisher_32":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"北見工業大学"}]},"item_2_select_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_select_item":"publisher"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"佐々木, 満雄"}],"nameIdentifiers":[{"nameIdentifier":"31800","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"岡, 宏"}],"nameIdentifiers":[{"nameIdentifier":"31801","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"井上, 貞信"}],"nameIdentifiers":[{"nameIdentifier":"31802","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2016-11-22"}],"displaytype":"detail","filename":"2-3-1.pdf","filesize":[{"value":"2.3 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"2-3-1.pdf","url":"https://kitami-it.repo.nii.ac.jp/record/6219/files/2-3-1.pdf"},"version_id":"ccd46b5c-c743-475f-b864-1b7a1f6724c1"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"三フッ化ホウ素を触媒とした泥炭フミン酸のスルホン化","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"三フッ化ホウ素を触媒とした泥炭フミン酸のスルホン化"}]},"item_type_id":"2","owner":"1","path":["22"],"pubdate":{"attribute_name":"公開日","attribute_value":"2007-04-09"},"publish_date":"2007-04-09","publish_status":"0","recid":"6219","relation_version_is_last":true,"title":["三フッ化ホウ素を触媒とした泥炭フミン酸のスルホン化"],"weko_creator_id":"1","weko_shared_id":3},"updated":"2022-12-13T02:19:33.701515+00:00"}