{"_buckets": {"deposit": "e354fc13-445a-4324-9287-f5fc8b0e994f"}, "_deposit": {"id": "6219", "owners": [], "pid": {"revision_id": 0, "type": "depid", "value": "6219"}, "status": "published"}, "_oai": {"id": "oai:kitami-it.repo.nii.ac.jp:00006219", "sets": ["22"]}, "item_2_alternative_title_18": {"attribute_name": "その他のタイトル", "attribute_value_mlt": [{"subitem_alternative_title": "The Sulfonation of Peat Humic Acid with Sulfuric Acid-Boron Trifluoride Complex"}]}, "item_2_biblio_info_6": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "1969-02", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "3", "bibliographicPageEnd": "370", "bibliographicPageStart": "365", "bibliographicVolumeNumber": "2", "bibliographic_titles": [{"bibliographic_title": "北見工業大学研究報告"}]}]}, "item_2_description_14": {"attribute_name": "フォーマット", "attribute_value_mlt": [{"subitem_description": "application/pdf", "subitem_description_type": "Other"}]}, "item_2_description_4": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "The sulfonation of peat humic acid with H_2S0_4-BF_3 complex was studied. The conditions of reaction were as follows. The BF_3/H_2S0_4，mol. ratios were 0.067, 0.134, 0.160, 0.186, 0.210, and 0.235 respectively, the experiments were treated at the reaction time of 10?360 min. and at the temp. of 20?150℃. The ion exchange capacity of sulfonation products was measured by 0.2 N CaCl_2 solution. The results of the above researchs were as follows. The best condition of reaction was shown in the case where BF_3/H_2S0_4 mol. Ratio was 0.134, reaction temp. was 100℃ and that reaction time was 90 min. At this condition of reaction was produced ion exchanger of which ion exchange capacity had been 1.35 m.eq./g.", "subitem_description_type": "Abstract"}]}, "item_2_full_name_3": {"attribute_name": "著者別名", "attribute_value_mlt": [{"nameIdentifiers": [{"nameIdentifier": "31803", "nameIdentifierScheme": "WEKO"}], "names": [{"name": "Mitsuo, SASAKI"}]}, {"nameIdentifiers": [{"nameIdentifier": "31804", "nameIdentifierScheme": "WEKO"}], "names": [{"name": "Hiroshi, OKA"}]}, {"nameIdentifiers": [{"nameIdentifier": "31805", "nameIdentifierScheme": "WEKO"}], "names": [{"name": "Sadanobu, INOUE"}]}]}, "item_2_publisher_32": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "北見工業大学"}]}, "item_2_select_15": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_select_item": "publisher"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "佐々木, 満雄"}], "nameIdentifiers": [{"nameIdentifier": "31800", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "岡, 宏"}], "nameIdentifiers": [{"nameIdentifier": "31801", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "井上, 貞信"}], "nameIdentifiers": [{"nameIdentifier": "31802", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2016-11-22"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "2-3-1.pdf", "filesize": [{"value": "2.3 MB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 2300000.0, "url": {"label": "2-3-1.pdf", "url": "https://kitami-it.repo.nii.ac.jp/record/6219/files/2-3-1.pdf"}, "version_id": "ccd46b5c-c743-475f-b864-1b7a1f6724c1"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "jpn"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "departmental bulletin paper", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "三フッ化ホウ素を触媒とした泥炭フミン酸のスルホン化", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "三フッ化ホウ素を触媒とした泥炭フミン酸のスルホン化"}]}, "item_type_id": "2", "owner": "1", "path": ["22"], "permalink_uri": "https://kitami-it.repo.nii.ac.jp/records/6219", "pubdate": {"attribute_name": "公開日", "attribute_value": "2007-04-09"}, "publish_date": "2007-04-09", "publish_status": "0", "recid": "6219", "relation": {}, "relation_version_is_last": true, "title": ["三フッ化ホウ素を触媒とした泥炭フミン酸のスルホン化"], "weko_shared_id": 3}