2026-03-15T01:51:24Z https://kitami-it.repo.nii.ac.jp/oai

oai:kitami-it.repo.nii.ac.jp:00006484 2025-01-30T05:22:36Z 7:15:32

Reaction of Benzyl Chloride with Ethylenediamine Cobalt(II) Complex in the presence of Sodium Borohydride 水素化ホウ素ナトリウムの存在下におけるエチレンジアミン･コバルト(II)錯体と塩化ベンジルとの反応 新井, 義夫 32775 見陣, 章彦 32776 application/pdf The reaction of benzyl chloride with ethylenediamine cobalt(II) complex was studied in the presence of sodium borohydride in alcohol under nitrogen atmosphere. Dibenzyl was produced selectively. Since molar ratio of converted benzyl chloride to the cobalt complex was nearly one, it was considered that the cobalt(I) species generated by the reduction with sodium borohydride react with benzyl chloyide to give benzyl radical which could couple to dibenzyl. departmental bulletin paper 北見工業大学 1979-10 application/pdf 北見工業大学研究報告 1 11 105 112 https://kitami-it.repo.nii.ac.jp/record/6484/files/11-1-10.pdf https://kitami-it.repo.nii.ac.jp/records/6484 jpn