2026-03-15T23:23:45Z https://kitami-it.repo.nii.ac.jp/oai

oai:kitami-it.repo.nii.ac.jp:00006149 2025-06-02T05:28:44Z 7:15:21

Synthesis of the Glycidyl Ethers from Perfumery Hydroxy Compounds 水酸基を有する香料化合物のグリシジルエーテル 伊藤, 呂明 31587 阿部, 和夫 31588 application/pdf Experiments are descrived on the synthesis of aroxy glycidyl ethers via the condensation of epichlorohydrin with perfumery hydroxy compounds. The reaction is catalysed by boron trifluoride，pyridine，sodium hydroxide and boron trifluoride being the most useful catalyst. The transfer of hydrogen chloride from a chlorohydrin to an α-epoxide take place readily in the presence of kalium hydroxide. Synthesized glycidyl ethers have various perfumery groups (Benzyl，Phenyl ethy1，d-Citronellyl， I-Menthyl) in the position of I aroxyl. Physical properties and spectra of these compounds are given in table III. departmental bulletin paper 北見工業大学 1963-03 application/pdf 北見工業大学研究報告 1 1 19 25 https://kitami-it.repo.nii.ac.jp/record/6149/files/1-1-2.pdf https://kitami-it.repo.nii.ac.jp/records/6149 jpn