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oai:kitami-it.repo.nii.ac.jp:00006484 2025-01-30T05:22:36Z 7:15:32

水素化ホウ素ナトリウムの存在下におけるエチレンジアミン･コバルト(II)錯体と塩化ベンジルとの反応 Reaction of Benzyl Chloride with Ethylenediamine Cobalt(II) Complex in the presence of Sodium Borohydride 新井, 義夫 見陣, 章彦 application/pdf The reaction of benzyl chloride with ethylenediamine cobalt(II) complex was studied in the presence of sodium borohydride in alcohol under nitrogen atmosphere. Dibenzyl was produced selectively. Since molar ratio of converted benzyl chloride to the cobalt complex was nearly one, it was considered that the cobalt(I) species generated by the reduction with sodium borohydride react with benzyl chloyide to give benzyl radical which could couple to dibenzyl. 北見工業大学 1979-10 jpn departmental bulletin paper https://kitami-it.repo.nii.ac.jp/records/6484 北見工業大学研究報告 11 1 105 112 https://kitami-it.repo.nii.ac.jp/record/6484/files/11-1-10.pdf application/pdf 3.1 MB 2016-11-22