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2022-12-13T02:20:38Z
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Synthesis of aryltriethoxysilanes via rhodium(I)-catalyzed cross-coupling of aryl electrophiles with triethoxysilane
Murata, Miki
Yamasaki, Hiyoruki
Ueta, Tsukasa
Nagata, Masayuki
Ishikura, Masanori
Watanabe, Shinji
Masuda, Yuzuru
open access
arylsilanes
hydrosilane
silylation
rhodium catalyst
The general and efficient silylation of aryl halides has developed utilizing triethoxysilane and a rhodium catalyst. The substrate scope is broad and includes ortho-, meta-, and para-substituted electron-rich and -deficient aryl iodides. In addition, the silylation of aryl bromides and fluoroalkanesulfonates proceeded in the presence of tetra-n-butylammonium iodide.
NOTICE: This is the author's version of a work accepted for publication by Elsevier. Changes resulting from the publishing process, including peer review, editing, corrections, structual formatting and other quality control mechanisms , may not be reflected in this document. Changes may have been to this work since it was submitted for publication.
application/pdf
Elsevier
2007-05-07
eng
journal article
AM
https://kitami-it.repo.nii.ac.jp/records/7236
https://doi.org/10.1016/j.tet.2007.02.103
Tetrahedron
63
19
4087
4094
https://kitami-it.repo.nii.ac.jp/record/7236/files/t63_4087-4094.pdf
application/pdf
362.2 kB
2016-11-22