2024-03-28T09:16:32Z
https://kitami-it.repo.nii.ac.jp/oai
oai:kitami-it.repo.nii.ac.jp:00006649
2022-12-13T02:19:59Z
7:15:42
Kinetics of Gas-Phase Hydration of Propene Heterogeneously Catalysed on a Solid Polymer Electrolyte*
Tohru, KANNO
Yukitoshi, TATSUMOTO
Masayoshi, KOBAYASHI
application/pdf
The kinetics of the hydration of propene on a Solid Polymer Electrolyte (SPE) and a silver-supported one have been studied by using the steady state and unsteady state methods at a temperature range of 100?160℃, using an ordinary now reactor under atmospheric pressure. The reaction gave two products in parallel reaction, iso-propylalcohol and hexane, and the reaction rates are represented as follows γ_<PγOH>=κPc_3H_6PH_2O^m andγ_<hex>=κPc_3H_6PH_2O^n with activation energies 46 and 90 kJ/mol, respectively. All the transient response curves caused by the concentration jump of propene gave a monotonic mode suggesting a Langmuir-Hinshelwood mechanism with the rate controlling step of carbenium ion formation.
北見工業大学
1989-11
eng
departmental bulletin paper
https://kitami-it.repo.nii.ac.jp/records/6649
北見工業大学研究報告
21
1
81
95
https://kitami-it.repo.nii.ac.jp/record/6649/files/21-1-6.pdf
application/pdf
5.5 MB
2016-11-22