2024-03-29T02:20:35Z
https://kitami-it.repo.nii.ac.jp/oai
oai:kitami-it.repo.nii.ac.jp:00006514
2022-12-13T02:19:52Z
7:15:33
Spectrophotometric Method for the Determination of Tetrabutylammonium ion*
Sadanobu, INOUE
Mitsuo, SASAKI
application/pdf
The extraction-spectropholometric determination of a trace amount of tetrabutylammonium ion (tba^+) with bis (maleonitriledithiolato) nickelate (II), Ni (mnt)^<2->_2 is described. Ni (mnt)^<2->_2 formed ion-pair with tba^+ and this was quantitatively extracted into chloroform (Kex=[tba^+_2, Ni (mnt)^<2->_2]_(0)/[Ni (mnt^<2->_2] [tba^+]^2=10^<13.89>]. The molar absorptivity of the ion-pair in chloroform was found to be 2.76×10^4 at 318 nm. Bee's law was confirmed in the range of 0?0.6μmol tba^/10cm~3 CHCL_3. Moderate amounts of most of the anions did not interfere with the determination. This method was also successfully applied to estimation of the ion-pair extraction constant.
北見工業大学
1981-03
eng
departmental bulletin paper
https://kitami-it.repo.nii.ac.jp/records/6514
北見工業大学研究報告
12
2
221
224
https://kitami-it.repo.nii.ac.jp/record/6514/files/12-2-8.pdf
application/pdf
1.8 MB
2016-11-22