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シアノコバルト（II）錯体水溶液によるニトロベンゼンのアゾキシベンゼンヘの還元 Reduction of Nitrobenzene to Azoxybenzene with the Aqueous Solution of Cobalt (II) Cyanide Complex 新井, 義夫 見陣, 章彦 application/pdf The reduction of nitrobenzene with the aqueous solution of cobalt (II)cyanide complex was carried out in nitrogen atmosphere, and the main product was azoxybenzene. The reaction mechanism was postulated as follows : PhNO_2+2H→PhNO+H_2O (1) PhNO+e→ＰｈＮO^-・ (２) 2(ＰｈＮＯ^-・)→__←O^-/ＰｈＮ-ＮＰｈ/O^- (3) O^-/PhN-NPh+H^+/O^-→PhN=NPh+OH^-/O^- (4) The transfer of electron and the liberation of proton from cobalt cyanide complex result from the above mechanism 北見工業大学 1969-02 jpn departmental bulletin paper https://kitami-it.repo.nii.ac.jp/records/6220 北見工業大学研究報告 2 3 371 377 https://kitami-it.repo.nii.ac.jp/record/6220/files/2-3-2.pdf application/pdf 2.6 MB 2016-11-22